Research of emulsion properties of oil with selection of effective chemical reagents for destruction of arising emulsions

T. Kuryakova, S. G. Bezryadin, Elena Yu. Klyukvina, L. Mezhueva
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Abstract

The presence of aggressive aqueous solutions of mineral salts leads to rapid wear of both oil pumping and refining equipment. Gas separation and preliminary water discharge are difficult. This is one of the reasons that it is necessary to dehydrate the oil emulsion from the moment it was formed, preventing its aging. The second most important reason for oil dehydration in the areas of its production is the high cost of transporting ballast-produced water. To determine the most suitable demulsifier used at the Tsarichansk field, a series of laboratory studies was conducted. According to the results of laboratory tests, it was found that the developed new multifunctional composite demulsifier Denmaster 3010, due to the synergism of the components that make up the composition, shows good dynamics of sediment compared to the base reagents and provides a high degree of emulsion destruction. According to the results of laboratory studies, the most effective in comparison with the basic reagent, both in the dynamics of dehydration and in the residual water content, is the multifunctional composition DenMaster 3010. Reagent DenMaster 3010 is composite demulsifier based on a mixture of organic and aromatic solvents with the addition of nonionic surfactants. Laboratory tests showed that DenMaster 3010 reagent provides a high degree of emulsion destruction at the stages of in-tube demulsification and preliminary discharge. According to the data obtained, when replacing the base reagent with the DenMaster 3010 reagent, at the stages of oil collection, stabilization and a decrease in the average values of water and salt content are observed, i.e. installation work is normalized.
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研究油的乳化特性,选择有效的化学试剂来破坏生成的乳剂
矿物盐的腐蚀性水溶液的存在导致抽油和精炼设备的快速磨损。气体分离和初步出水困难。这就是为什么从油乳液形成的那一刻起就必须脱水,以防止其老化的原因之一。在其生产地区造成石油脱水的第二个最重要的原因是运输压载采出水的高成本。为了确定在察里干斯克油田使用的最合适的破乳剂,进行了一系列的实验室研究。根据实验室试验结果,研制的新型多功能复合破乳剂Denmaster 3010,由于组成成分的协同作用,与基础试剂相比,表现出良好的沉积动力学,并提供了高度的乳液破坏。根据实验室研究结果,与碱性试剂相比,在脱水动力学和残余水分含量方面,最有效的是多功能组合物DenMaster 3010。试剂DenMaster 3010是一种复合破乳剂,基于有机和芳香溶剂的混合物,并添加非离子表面活性剂。实验室测试表明,DenMaster 3010试剂在管内破乳和初步排出阶段提供了高度的乳化液破坏。根据所获得的数据,当用DenMaster 3010试剂替换基础试剂时,在集油阶段,观察到水和盐含量的平均值稳定和下降,即安装工作正常化。
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