Study the effect of gamma ray on silver nanoparticles prepared by pulse laser ablation in liquid technique (PLAL)

Abstract

Silver nanoparticles in this study were prepared using the method of laser ablation in liquids (PLAL) at two energies (540 and 700) mJ and the count of pulses were (100,200,300 and 400) pulse . The prepared samples were divided into three groups: the first group of the samples were kept as they are without any irradiation but the second and third group were irradiated by Co-60 source with two amount of doses (7.5 and 11) KGy respectively . A series of measurements and studies were done , and from the pictures of Transmitted Electron Microscope (TEM) , it was observed that the prepared nanoparticles at laser energy (540) mJ with pulses count (400) pulse were spherical but the prepared nanoparticles at laser (700) mJ with pulses cont (400) pulse were nano rods shape. The gamma irradiation effect was studied through its effect on the optical properties of the nanoparticles at different preparation conditions , represented by a change in the pulses and the energy of the laser used. The results showed that there was an increase the absorbance peaks when increasing the irradiated dose. The (TEM) image showed we get spherical nanoparticles in shape and nano composition. The average diameter of the prepared silver nanoparticles at (540) mJ laser energy in the range of (30-40) nm.