Supramolecular Complexes between Fullerene [60]- and [70], and resorcinarene

G. Martinez, Cabañas R Teran, Ochoa A Tlapanco, A. Toscano, R. Cruz-Almanza
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引用次数: 13

Abstract

Abstract New complexes 2 and 3 between [60]- and [70] fullerenes with resorcinarene 1 were prepared and characterized by spectroscopic methods. Resorcinarene 1 was studied in solution by NMR and in the solid state by CP-MAS NMR and X-ray diffraction. The macrocycle 1 can guest one [60]- or [70] fullerene molecule in its structure. For the complexes 2 and 3, π-π, CH-π and n-π interactions were observed by 13C CP-MAS and FTIR analysis data.
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富勒烯[60]-和间苯二甲酸[70]之间的超分子配合物
摘要制备了[60]-和[70]富勒烯与间苯二甲酸1之间新的配合物2和3,并用光谱方法对其进行了表征。间苯二甲酸乙酯1在溶液中通过核磁共振和固体中通过CP-MAS核磁共振和x射线衍射进行了研究。大环1可以在其结构中加入一个[60]-或[70]富勒烯分子。对于配合物2和3,用13C CP-MAS和FTIR分析数据观察了π-π、CH-π和n-π的相互作用。
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