Potential barrier at the ferroelectric grain boundary due to asymmetric screening of depolarization fields

Y. Genenko, O. Hirsch, P. Erhart
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Abstract

Electric depolarization fields generated by a stripe domain structure in ferroelectrics are considered within a semiconductor model. Field screening due to electronic band bending and due to presence of intrinsic defects leads to the building of asymmetric space charge regions near the grain boundary. This in turn results in the formation of a potential barrier between the grain surface and its interior.
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退极化场不对称筛选导致的铁电晶界势垒
在半导体模型中考虑了铁电体中由条纹畴结构产生的去极化场。由于电子能带弯曲和本征缺陷的存在而产生的场屏蔽导致在晶界附近形成不对称空间电荷区。这反过来又导致在颗粒表面和内部之间形成电位屏障。
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