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Vibrational fingerprints of LiNbO3-LiTaO3 mixed crystals LiNbO3-LiTaO3混合晶体的振动指纹图谱
Pub Date : 2013-01-01 DOI: 10.1080/00150193.2013.821893
S. Sanna, A. Riefer, S. Neufeld, W. Schmidt, G. Berth, A. Widhalm, A. Zrenner
The structural and vibrational properties of lithium niobate (LN) - lithium tantalate (LT) mixed crystals (LNT, LiNb1-xTaxO3) are investigated over the whole composition range by first-principles simulations. The crystal volume grows roughly linearly from LT to LN, whereby the lattice parameters a and c show minor deviations from the Vegard behavior between the end-compounds, LiNbO3 and LiTaO3. Our calculations in the framework of the density functional theory show the TO1, TO2 and TO4-modes to become harder with increasing Nb concentration. TO3 becomes softer with increasing Nb content, instead. The frequency shifts of the zone center A1-TO phonon modes for crystals with different compositions are found to be as large as 30 cm-1. Raman spectroscopy, which is sensitive to the A1 modes, can be therefore employed to determine the crystal composition.
利用第一性原理模拟研究了铌酸锂(LN) -钽酸锂(LT)混合晶体(LNT, LiNb1-xTaxO3)在整个组成范围内的结构和振动特性。晶体体积从LT到LN大致呈线性增长,晶格参数a和c与末端化合物LiNbO3和LiTaO3之间的Vegard行为有轻微偏差。我们在密度泛函理论框架下的计算表明,随着Nb浓度的增加,TO1、TO2和to4模式变得更硬。相反,随着Nb含量的增加,TO3变软。不同成分晶体的区中心A1-TO声子模的频移可达30 cm-1。因此,对A1模式敏感的拉曼光谱可以用来确定晶体的组成。
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引用次数: 7
Dielectric and piezoelectric properties of modified (Na, K)NbO3 ceramics substituted with KNbO3 用KNbO3取代改性(Na, K)NbO3陶瓷的介电和压电性能
Pub Date : 2013-01-01 DOI: 10.1080/00150193.2013.822776
Sunmin Byenon, Juhyun Yoo
In this study, (1-x)[(Li0.04(Na0.56K0.44)0.96(Nb0.90Ta0.10) 0.998Zn0.005O3)]-xKNbO3 (x = 0 ~ 7.5 mol%) composition ceramics were fabricated by a conventional sintering technique. The influences of KNbO3 on the dielectric and piezoelectric properties of the ceramics were investigated. Optimum physical properties of piezoelectric constant d33 = 255 [pC/N], electromechanical coupling factor kp = 0.4358, dielectric constant εr= 699, measured density (ρ)= 4.49 [g/cm3] were obtained from the composition ceramic with x = 3[mol%]. These results indicate that the (1-x) LNKLNTZ-xKN ceramic is a promising lead-free piezoelectric candidate material for practical applications.
采用常规烧结法制备了(1-x)[(Li0.04(Na0.56K0.44)0.96(Nb0.90Ta0.10) 0.998 zn0.0050 o3)]-xKNbO3 (x = 0 ~ 7.5 mol%)复合陶瓷。研究了KNbO3对陶瓷介电和压电性能的影响。当x = 3[mol%]时,获得了压电常数d33 = 255 [pC/N],机电耦合系数kp = 0.4358,介电常数εr= 699,测量密度(ρ)= 4.49 [g/cm3]的最佳物理性能。这些结果表明,(1-x) LNKLNTZ-xKN陶瓷是一种具有实际应用前景的无铅压电候选材料。
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引用次数: 0
Fe valence determination in doped SrTiO3 epitaxial films 掺杂SrTiO3外延膜中铁价的测定
Pub Date : 2012-09-10 DOI: 10.1109/ISAF.2012.6297843
D. Kajewski, J. Szade, J. Kubacki, K. Szot, A. Kohl, C. Lenser, R. Dittmann
Atomic Force Microscopy (AFM) measurements have been performed for Fe doped SrTiO3 thin films with an Fe concentration of 2 and 5 at%. Thin films with a thickness of about 20 nm were grown by pulsed laser deposition on single crystalline SrTi0.99Nb0.01O3 substrates. Low-energy electron diffraction examination showed that the films are single crystalline. The regions treated with the AFM tip (applied dc voltage up to 6V) showed inhomogeneity of the electrical conductivity.
原子力显微镜(AFM)测量了铁掺杂SrTiO3薄膜,铁浓度为2%和5%。采用脉冲激光沉积技术在单晶srti0.99 nb0.010 o3衬底上生长出厚度约为20 nm的薄膜。低能电子衍射检测表明薄膜为单晶。AFM尖端处理的区域(施加直流电压高达6V)显示出电导率的不均匀性。
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引用次数: 0
Electrical properties and impedance spectroscopy of modified potassium sodium niobate ceramics 改性铌酸钾钠陶瓷的电学性能和阻抗谱
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297815
E. M. Alkoy, A. B. Yavuz, D. Avdan, S. Alkoy
Lead-free potassium sodium niobate (KNN) ceramics were prepared with lithium modification. Copper oxide was also added as sintering aid. Impedance spectroscopy was used as a tool to analyze electrical behavior of ceramics as a function of frequency from 100 Hz to 10 MHz at various temperatures.
采用锂改性法制备无铅铌酸钾钠(KNN)陶瓷。还加入氧化铜作为助烧剂。阻抗谱是一种分析陶瓷在不同温度下的电学行为的工具,其频率范围从100 Hz到10 MHz。
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引用次数: 0
Ultra wide band elastic resonators and their application: SH0 mode plate wave resonators with ultra wide bandwidth of 29 % 超宽带弹性谐振器及其应用:超宽带29%的SH0型板波谐振器
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297740
M. Kadota, T. Ogami, T. Kimura
Currently, an ultra wide band resonator to realize a tunable filter with a wide tunable range is strongly required, because a mobile phone with multi-bands and a cognitive radio system require such tunable filters to simplify their circuits. This time, authors realized resonators with ultra wide bandwidths of 26 to 29 % and a large impedance ratio of 92 to 98 dB between resonant and anti-resonant frequencies using an SH0 plate wave in a LiNbO3 plate. In addition, a band pass type tunable filter with a tunable range of 16 to 18 % was realized using the resonators.
目前,迫切需要超宽带谐振器来实现具有宽可调谐范围的可调谐滤波器,因为具有多频段的移动电话和认知无线电系统需要这种可调谐滤波器来简化电路。这一次,作者在LiNbO3板中使用SH0板波实现了26 ~ 29%的超宽带宽和92 ~ 98 dB的谐振和反谐振频率之间的大阻抗比。此外,利用该谐振器实现了可调范围为16% ~ 18%的带通型可调谐滤波器。
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引用次数: 8
Robust structural health monitoring transducers based on LTCC/PZT multilayer 基于LTCC/PZT多层结构的鲁棒健康监测传感器
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297864
S. Gebhardt, M. Flossel, A. Schonecker, U. Lieske, T. Klesse
Structural Health Monitoring (SHM) systems allow for permanent and online characterization of condition and health of structural components. We introduce novel SHM modules fully based on inorganic materials which show a distinguished improve of temperature and chemical stability compared to known piezoceramic-polymer-patches. Using ceramic multilayer technology lead zirconate titanate (PZT) discs are integrated into a package of low temperature cofired ceramic (LTCC) sheets enabling for the production of compact ultrasonic transducers with integrated electronic circuits and signal processing units.
结构健康监测(SHM)系统允许永久和在线表征结构部件的状态和健康。我们介绍了完全基于无机材料的新型SHM模块,与已知的压电陶瓷聚合物贴片相比,该模块在温度和化学稳定性方面有显著改善。采用陶瓷多层技术,将锆钛酸铅(PZT)圆盘集成到低温共烧陶瓷(LTCC)片的封装中,从而可以生产具有集成电子电路和信号处理单元的紧凑超声波换能器。
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引用次数: 3
Semiconducting behavior of CaO-added BaTiO3-(Bi1/2Na1/2)TiO3 solid solution ceramics 添加cao的BaTiO3-(Bi1/2Na1/2)TiO3固溶体陶瓷的半导体行为
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297799
H. Takeda, H. Akutsu, M. Zubair, T. Hoshina, T. Tsurumi
We report synthesis of BaTiO3-(Bi1/2Na1/2)TiO3 (BT-BNT) semiconducting ceramics by conventional solid-state reaction method in air atmosphere. By adding CaO into the calcined BT-BNT powder, the resulting ceramics acquires the semiconductivity with the resistivity at room temperature ρRT value of 102-103 Ωcm and PTC behavior. The structure analysis using X-ray diffraction method, it was found that the CaO added BT-BNT ceramics consisted of perovskite-type ABO3 single phase. Chemical composition analysis by inductively coupled plasma spectrometry disclosed a distinct evaporation of Na and Bi during sintering process. The quantity of evaporation of Na was higher than that of Bi. Based on these results, it was suggested that dominant substitution of Ca2+ for Na+ in the A site occurred, and then that part of Bi3+ separated from divalent (Bi1/2Na1/2)2+ pairs worked as a donor.
报道了在空气气氛中采用常规固相反应法制备BaTiO3-(Bi1/2Na1/2)TiO3 (BT-BNT)半导体陶瓷。在焙烧BT-BNT粉末中加入CaO,得到的陶瓷具有半导体性,室温ρRT值为102 ~ 103 Ωcm,且具有PTC行为。采用x射线衍射法进行结构分析,发现CaO加入后的BT-BNT陶瓷由钙钛矿型ABO3单相组成。通过电感耦合等离子体光谱分析发现,在烧结过程中Na和Bi有明显的蒸发。Na的蒸发量大于Bi。基于这些结果,我们认为在A位点发生了Ca2+对Na+的显性取代,然后从二价(Bi1/2Na1/2)2+对分离的部分Bi3+作为供体。
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引用次数: 0
Mechanism of texture development in <001> oriented (K, Na)NbO3-based ceramics 取向(K, Na) nbo3基陶瓷织构发育机理
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297773
A. Kikuchihara, T. Kimura
The development of grain orientation was examined for (K, Na)NbO3-based ceramics using two kinds of platelike NaNbO3 template powders made by single- and two-step molten salt synthesis (MSS) and four kinds of matrix powders to examine the factors controlling the degree of orientation. The template grains made by single-step MSS were dissolved in the matrix of a mixture of NaNbO3 and KNbO3 powders, leaving large voids. The template grains made by two-step MSS were not dissolved and gave high reproducibility in the degree of orientation. The effect of matrix species on the grain orientation was examined using the template powder made by two-step MSS and the matrixes of KNbO3, NaNbO3, and (K0.5Na0.5)NbO3 powders and a mixture of KNbO3 and NaNbO3 powders. The extensive grain orientation developed only in (K0.5Na0.5)NbO3 and a mixture of KNbO3 and NaNbO3 powders. The origin of the difference in the grain orientation behavior was examined by microstructure observation.
采用单步熔盐合成(MSS)和两步熔盐合成(MSS)制备的两种片状NaNbO3模板粉和四种基体粉,考察了(K, Na) nbo3基陶瓷的晶粒取向发展,考察了取向程度的控制因素。单步MSS制备的模板颗粒溶解在NaNbO3和KNbO3粉末混合物的基质中,留下较大的空隙。两步MSS制备的模板颗粒不溶解,取向度重现性好。以KNbO3、NaNbO3和(K0.5Na0.5)NbO3为基体,以及KNbO3和NaNbO3粉末的混合物为模板粉,采用两步MSS法制备模板粉,考察了基体种类对晶粒取向的影响。只有在(K0.5Na0.5)NbO3和KNbO3和NaNbO3混合粉末中才出现了广泛的晶粒取向。通过显微组织观察分析了晶粒取向行为差异的原因。
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引用次数: 1
Fabrication and characterization of photorefractive platforms in lithium niobate for recording of integrated holographic devices 集成全息器件记录用铌酸锂光折变平台的制备与表征
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297734
M. Bazzan, M. Ciampolillo, A. Zaltron, N. Argiolas, C. Sada, N. Kokanian, Marc D. Fontana
Local doping by Fe in-diffusion in lithium niobate is a powerful technique to create regions of high photorefractive sensitivity useful to fabricate holographic optical elements such as filters, demultiplexers, Bragg mirrors and so on. In this paper the fabrication and characterization of such regions are reviewed, giving practical advices about how to proceed to realize such areas with the required characteristics.
铌酸锂中的Fe扩散局部掺杂是一种强大的技术,可以产生高光折变灵敏度区域,用于制作滤光片、解复用器、布拉格反射镜等全息光学元件。本文综述了此类区域的制备和表征方法,并就如何进一步实现具有所需特性的此类区域提出了实用的建议。
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引用次数: 1
Composition profiling of piezoelectric PZT thin films deposited onto Cu coated polymer substrates 镀铜聚合物基板上PZT压电薄膜的成分分析
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297777
A. Kleiner, G. Suchaneck, B. Adolphi, G. Gerlach, V. Lavrentiev, Z. Hubička, M. Čada, L. Jastrabík, A. Dejneka
In this work, we investigate the composition profile of nanocrystalline Pb(Zr, Ti)O3 (PZT) thin films deposited by means of reactive magnetron sputtering from 200 mm diameter metallic targets (Pb, Ti, Zr). High-power pulse sputtering has been employed for alternatively the Zr- or Ti-target. Composition analysis and profiling was performed by means of X-ray photoelectron spectroscopy (XPS) and Rutherford backscattering (RBS). RBS data was recalibrated to exclude hydrogen content not determined by XPS. Advantages and drawbacks of both methods for PZT composition profiling are discussed.
本文研究了以直径200 mm的金属靶(Pb, Ti, Zr)为基体,采用反应磁控溅射法制备Pb(Zr, Ti)O3 (PZT)纳米晶薄膜的组成。采用高功率脉冲溅射技术交替制备Zr或ti靶。采用x射线光电子能谱(XPS)和卢瑟福后向散射(RBS)对样品进行了成分分析。重新校准RBS数据以排除非XPS测定的氢含量。讨论了两种方法在PZT成分分析中的优缺点。
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引用次数: 0
期刊
Proceedings of ISAF-ECAPD-PFM 2012
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