Brewster Angle Microscope and Atomic Force Microscopy Study of Poly 4-(n-Methacyloyl)-Disperse Red 1-Methacrylic Acid Monolayer at the Air/Water Interface and on the Glass Surface

Y. Kang, Sang-Do An
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Abstract

Abstract Derivatives of azobenzene cause photoisomerization when they are illuminated with UV-vis light. We investigated the photoisomerization of azobenzene derivatives for holographic memory. Organic films containing amphiphile azobenzene derivatives can be applied in molecular devices by changing energy of molecular level, refractive index. In order to investigate of photoisomerization of azobenzene derivatives at the air/water interface, azobenzene derivatives having side chain copolymer containing methacrylic acid [poly 4-(n-methacryloyl)-Disperse Red 1-methacrylic acid (pDRIMA)] was synthesized. The film of azobenzene derivative was characterized by the measurements of Brewster Angle Microscope (BAM) images at the air/water interface and Atomic Force Microscopy (AFM) images on the glass substrate.
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空气/水界面和玻璃表面聚4-(n-甲基酰基)-分散红1-甲基丙烯酸单层膜的布鲁斯特角显微镜和原子力显微镜研究
偶氮苯衍生物在紫外光照射下会发生光异构化。研究了偶氮苯衍生物在全息记忆中的光异构化。含两亲性偶氮苯衍生物的有机薄膜可以通过改变分子能级的能量、折射率来应用于分子器件。为了研究偶氮苯衍生物在空气/水界面上的光异构化,合成了含有甲基丙烯酸侧链共聚物的偶氮苯衍生物[聚4-(n-甲基丙烯酰)-分散红1-甲基丙烯酸(pDRIMA)]。利用空气/水界面的Brewster角显微镜(BAM)图像和玻璃基板上的原子力显微镜(AFM)图像对偶氮苯衍生物薄膜进行了表征。
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