High Thermal Conductive Adhesive Sheet with Low Dielectric Constant

Masao Tomikawa, Akira Shimada, Yoichi Shimba
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Abstract

High thermal conductive adhesive sheet whose dielectric constant (Dk) is 5.0 was developed. To obtain low Dk. low Dk matrix polyimide resin whose Dk is 2.6 was designed to decrease Dk as much as possible. To obtain high thermal conductivity, h-BN sphere shaped filler was used as a main heat thermal conductive filler. The h-BN sphere shaped filler shows high thermal conductivity (40W/mK) as bulk filler and low Dk (4.0). High thermal conductive adhesive was obtained by mixing the h-BN cohesive filler into the low Dk polyimide matrix resinIn addition, to make heat path in the high thermal conductive adhesive to z-direction, AlN whisker was oriented to z-direction in the thermal conductive adhesive. We successfully developed novel method to disperse AlN whiskers to z-direction preferably. By utilizing the alignment method, thermal conductivity of the materials increased drastically.As a result, the heat conductive sheet shows the heat conductivity of 15W/mK with low dielectric constant. In addition, the sheet shows excellent break down voltage. The adhesive sheet is suitable for Thermal Interface Material (TIM) for high voltage power modules.
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低介电常数高导热粘接片材
研制了介电常数(Dk)为5.0的高导热胶粘片。获得低Dk。设计了低Dk基聚酰亚胺树脂,其Dk为2.6,以尽量降低Dk。为了获得较高的导热系数,采用h-BN球形填料作为主要的导热填料。h-BN球形填料具有高导热系数(40W/mK)和低Dk(4.0)的特点。在低Dk聚酰亚胺基体树脂中加入h-BN黏结填料,得到高导热胶粘剂,使高导热胶粘剂中的热路向z方向移动,AlN晶须在导热胶粘剂中向z方向移动。我们成功地开发了一种新颖的方法,使AlN晶须向z方向分散。利用定向方法,材料的导热系数显著提高。结果表明,该导热片的导热系数为15W/mK,且介电常数较低。此外,该板具有优异的击穿电压。适用于高压电源模块的热界面材料(TIM)。
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