Shi Dongpo, Yin Xianqing, Zheng Yan-cheng, Chen Wu, Fu Jiaxin, Ren Zhaohua
{"title":"Transition Metal-free Epoxidation of Alkenes Based on the Existence of (2- hydroxypropyl)-β-CD","authors":"Shi Dongpo, Yin Xianqing, Zheng Yan-cheng, Chen Wu, Fu Jiaxin, Ren Zhaohua","doi":"10.2174/1874123101509010020","DOIUrl":null,"url":null,"abstract":"A green, efficient epoxidation of alkenes with hydrogen peroxide (H2O2) and sodium bicarbonate (NaHCO3) catalyzed by (2-hydroxypropyl)--cyclodextrin (2-hp--CD) in aqueous solution has been investigated in detail. A range of alkenes were epoxidized at ambient temperature with high yields.","PeriodicalId":22933,"journal":{"name":"The Open Chemical Engineering Journal","volume":"8 1","pages":"20-24"},"PeriodicalIF":0.0000,"publicationDate":"2015-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Open Chemical Engineering Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/1874123101509010020","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
A green, efficient epoxidation of alkenes with hydrogen peroxide (H2O2) and sodium bicarbonate (NaHCO3) catalyzed by (2-hydroxypropyl)--cyclodextrin (2-hp--CD) in aqueous solution has been investigated in detail. A range of alkenes were epoxidized at ambient temperature with high yields.
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