Physical closed action for heavy metal in sludge by solidified disposal

Lei Li
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Abstract

Heavy metal could be closed in crystal lattice of hydrate or absorbed in surface of hydrate by solidified disposal, which could be named Physical closed action. Physical or chemical action maybe destroy the integrality of hydrate induce the leaching of heavy metal when the solidified sludge was utilized or landfilled. The XRD was used to analyze the integrality of hydrate crystal after the solidified sludge crushed and the leaching test of heavy metal was carried out. The result shows that the physical closed action was valid when grain diameters of solidified sludge exceed 1.0mm though the integrality of hydrate crystal was damaged. But the leaching quantity of heavy metal would increase with the crushed degree increased.
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固化处置对污泥中重金属的物理封闭作用
重金属可以在水合物的晶格中被封闭,也可以通过固化处理在水合物表面被吸附,这可以称为物理封闭作用。固化污泥在利用或填埋时,其物理或化学作用可能破坏水合物的完整性,导致重金属的浸出。采用XRD分析了固化污泥破碎后水合物结晶的完整性,并进行了重金属的浸出试验。结果表明:当固化污泥粒径大于1.0mm时,物理封闭作用有效,但破坏了水合物晶体的完整性;但重金属的浸出量随破碎程度的增加而增加。
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