Investigation the plating and wetting ability of reactive sputtered Molybdenum-Tungsten multi-layers for advanced Cu metallization

T. Kuo, T. Shih, Yin-Hsien Su, Wen-Hsi Lee, W. Liao
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Abstract

Molybdenum-Tungsten (MoxW) alloy films were deposited on SiO2 substrates by reactive sputtering. Direct electroplating Cu on Molybdenum-Tungsten alloy films and annealing in N2 were carried out. In this study, the effect of electroplating time and annealing temperature on the structural, plating and wetting ability of Molybdenum-Tungsten alloy films was investigated. The films were characterized by X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM). The results show that Cu can be directly electroplated on Molybdenum-Tungsten alloy films with uniform nucleation. After annealing, de-wetting behavior of Molybdenum-Tungsten alloy films are shown to be better than Ta even up to 500°C.
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研究了反应溅射钼钨多层膜的电镀和润湿性能
采用反应溅射法在SiO2衬底上制备了钼钨合金薄膜。在钼钨合金薄膜上直接电镀Cu,并在N2中退火。研究了电镀时间和退火温度对钼钨合金薄膜结构、镀层和润湿性能的影响。采用x射线光电子能谱(XPS)和扫描电镜(SEM)对膜进行了表征。结果表明,Cu可以直接电镀在钼钨合金薄膜上,且成核均匀。退火后,钼钨合金薄膜的脱湿性能优于Ta,即使温度高达500℃。
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