Development of Thin Film Formation Technique Using Ion Irradiation Effect Control in Sputtering Method

H. Toyota
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Abstract

We fabricated Ni ˆlms on a Polyimide (PI) ˆlm and an Acrylonitrile-Butadiene-Styrene (ABS) resin substrate using unbalanced magnetron sputtering assisted by inductively coupled plasma. For the PI ˆlm, the eŠect of ion irradiation was controlled by substrate DC bias VS and magnetic ‰ux density toward the substrate BC. For the ABS resin substrate, the eŠect of ion irradiation was controlled by target DC power PT and magnetic ‰ux density toward the substrate BC. For each substrate, we investigated the eŠect of ion irradiation on the Ni ˆlm structures in detail. The eŠect of ion irradiation E was estimated by measured physical quantities with respect to sputtered atom ‰ux, ion ‰ux and ion energy. From xray diŠraction measurement, the crystallite size t(111) increased with the eŠect of ion irradiation. Minimum ˆlm resistivities of 9.0×10-6 and 1.4×10-5 Qcm were measured for BC=3 mT and E=0.24 on the PI ˆlm and BC=5 mT and E=0.98 on the ABS resin substrate, respectively. We conclude that controlling the eŠect of ion irradiation is eŠective for high quality Ni ˆlm formation on the PI ˆlm and the ABS resin substrate.
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溅射法中离子辐照效应控制薄膜形成技术的发展
我们在聚酰亚胺(PI)薄膜和丙烯腈-丁二烯-苯乙烯(ABS)树脂衬底上利用电感耦合等离子体辅助的不平衡磁控溅射制备了Ni - lms。对于PI - lm,离子辐照的eŠect由衬底直流偏置VS和向衬底BC的磁密度‰ux控制。对于ABS树脂基材,离子辐照的eŠect由目标直流功率PT和对基材BC的磁密度控制。对于每种衬底,我们详细研究了离子辐照对Ni - lm结构的eŠect影响。离子辐照E的eŠect是通过对溅射原子‰ux、离子‰ux和离子能量的测量物理量来估计的。从x射线diŠraction测量可知,随着离子辐照eŠect,晶体尺寸t(111)增大。当BC=3 mT, E=0.24, BC=5 mT, E=0.98时,分别测量了9.0×10-6和1.4×10-5 Qcm的最小λ lm电阻率。我们得出结论:控制离子辐照的eŠect是在PI - m和ABS树脂基体上形成高质量Ni - m的eŠective。
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