spraying parameters optimization for wear and abrasion resistance of Cr2O3 coating deposited with cascaded plasma torch

J. Antoš, K. Lencová, P. Šulcová, A. Keslová, J. Duliškovič
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Abstract

Atmospheric plasma sprayed (APS) chromia coating provides excellent wear behaviour combined with corrosion resistance even in aggressive environments. In this paper, the influence of variable spraying parameters on the mechanical properties and microstructure of chromia coatings is investigated. Main goal for this optimization is to achieve high wear and abrasive resistance. APS ceramic coatings such as chromia could perform in some industrial applications as well as more commonly used HVOF (high velocity oxygen fuel) cermet coatings, especially in wear and abrasion resistance. In order to be able to compete with hard and wear resistant cermet HVOF coatings, optimization of spraying parameters for this particular chromia powder is required. High throughput cascaded plasma troch is used for the spraying process. Set of five different spraying parameters is used varying only primary plasma gas flow rate and input electrical current with rest of spraying parameters set constant, including carrier gas flow. Critical plasma spraying parameter or CPSP is also utilized in the design stage of experiment. Coatings sprayed on low carbon steel substrate underwent superficial Rockwell indentation, optical microscopy on polished cross section, adhesion strength testing and dry sand abrasion test. No significant correlation between CPSP values and hardness, adhesive strength or abrasion resistance was observed. High input electrical current combined with rather high plasma gas flow provided better abrasion resistance than lower input electrical current and flow rates. Coating performing best in abrasion test also displayed by far the highest adhesive strength to substrate material, so presumably having also the highest cohesion strength between splats may lead to less inter splat decohesion or chipping during dry sand abrasion.
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级联等离子炬沉积Cr2O3涂层耐磨性能的喷涂参数优化
大气等离子喷涂(APS)铬涂层即使在腐蚀性环境中也具有优异的耐磨性能和耐腐蚀性。本文研究了不同喷涂参数对含铬涂层力学性能和显微组织的影响。这种优化的主要目标是实现高耐磨和耐磨性。APS陶瓷涂层,如chromia,可以在一些工业应用中以及更常用的HVOF(高速氧燃料)陶瓷涂层中发挥作用,特别是在耐磨和耐磨性方面。为了能够与坚硬耐磨的金属陶瓷HVOF涂层竞争,需要优化这种特殊铬粉的喷涂参数。喷涂过程采用高通量级联等离子体喷管。使用一组五种不同的喷涂参数,仅改变主等离子体气体流速和输入电流,其余喷涂参数(包括载气流量)保持不变。在实验设计阶段也采用了临界等离子喷涂参数(CPSP)。对喷涂在低碳钢基体上的涂层进行表面洛氏压痕、抛光截面光学显微镜、附着强度测试和干砂磨损测试。CPSP值与硬度、粘接强度、耐磨性无显著相关性。高输入电流结合相当高的等离子体气体流量比低输入电流和流量提供更好的耐磨性。在磨损测试中表现最好的涂层与基材的结合强度也是最高的,因此可以推测,在干砂磨损过程中,片间的内聚强度也最高,可能导致片间的脱粘或碎裂的减少。
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