Surface modification of β-MnO2 nanorods as nanolubricant

Y. Attia, Gamal El-ghannam
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Abstract

Nanolubricants are substances that use nanoparticles as lubricant additives. The proposal for wear reduction has piqued interest in nanolubricants. Particle agglomeration is the main drawback of using nanomaterials as lubricating oil additives, and creating novel nanolubricants is one of the most difficult challenges. Evaluation of the nano β-MnO2 nanorods as nanoadditives for enhancing lubricating oil characteristics. After producing β-MnO2 nanorods by a modified hydrothermal process, oleic acid was used to modify their surfaces. Next, the physical and tribological characteristics of lubricating oil before and after the addition of nanoadditives were assessed. The physical parameters of lubricating oil, including flash point, pour point, thermal stability, antiwear ability, and viscosity, were all improved by varying concentrations of surface-modified MnO2 nanorods by rates 8.19%, 50%, 63.04%, 10.9%, 8.96% at 40ºC and 4.18% at 100ºC, respectively. The findings demonstrate that the shear strain is reduced and an anti-wear boundary coating is created as a result of the deposition of nanoparticles produced by tribochemical reaction products during the friction process. The development of a protective film using nanoadditives improves lubricant requirements, ushering in a revolution in the lubricant industry.
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β-二氧化锰纳米棒作为纳米润滑剂的表面改性
纳米润滑剂是使用纳米颗粒作为润滑剂添加剂的物质。减少磨损的提议激起了人们对纳米润滑剂的兴趣。颗粒团聚是纳米材料作为润滑油添加剂的主要缺点,而制造新型纳米润滑剂是最困难的挑战之一。纳米β-二氧化锰纳米棒作为提高润滑油特性的纳米添加剂的评价。采用改性水热法制备β-MnO2纳米棒后,采用油酸对其表面进行修饰。其次,对添加纳米添加剂前后润滑油的物理和摩擦学特性进行了评价。不同浓度的表面改性二氧化锰纳米棒对润滑油的闪点、倒点、热稳定性、抗磨性能和粘度的改善率分别为8.19%、50%、63.04%、10.9%、8.96%(40℃)和4.18%(100℃)。研究结果表明,摩擦过程中摩擦化学反应产物产生的纳米颗粒沉积,减少了剪切应变,形成了抗磨损的边界涂层。使用纳米添加剂的保护膜的开发提高了润滑剂的要求,在润滑剂行业迎来了一场革命。
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来源期刊
Nanoscience and Nanotechnology - Asia
Nanoscience and Nanotechnology - Asia Engineering-Engineering (all)
CiteScore
1.90
自引率
0.00%
发文量
35
期刊介绍: Nanoscience & Nanotechnology-Asia publishes expert reviews, original research articles, letters and guest edited issues on all the most recent advances in nanoscience and nanotechnology with an emphasis on research in Asia and Japan. All aspects of the field are represented including chemistry, physics, materials science, biology and engineering mainly covering the following; synthesis, characterization, assembly, theory, and simulation of nanostructures (nanomaterials and assemblies, nanodevices, nano-bubbles, nano-droplets, nanofluidics, and self-assembled structures), nanofabrication, nanobiotechnology, nanomedicine and methods and tools for nanoscience and nanotechnology.
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