Synthesis, characterization and 2,5-pyridinedicarboxylic acid interaction of Zinc(II) complexes with N-(4-X-phenyl)pyridine-2-yl-methanimine ligands (X= -Cl and -N(CH3)2)
{"title":"Synthesis, characterization and 2,5-pyridinedicarboxylic acid interaction of Zinc(II) complexes with N-(4-X-phenyl)pyridine-2-yl-methanimine ligands (X= -Cl and -N(CH3)2)","authors":"N. Dinamarca, M. Azócar, P. Levín, H. Muñoz","doi":"10.21060/cis.v5i2.2692","DOIUrl":null,"url":null,"abstract":"Abstract: Two new Zn(II) N-(4-X-phenyl)pyridine-2-yl-methanimine complexes, [Zn(NN´-Cl)Cl 2 ]( 1 ) and [Zn(NN´-N(CH 3 ) 2 )Cl 2 ]( 2 ), have been synthesized and characterized by elemental analysis, FT-IR and NMR- 1 H spectra. The crystal structure of complex 1 was determined by X-ray single crystal diffraction. Experiments performed by Benesi-Hilderbrand method indicate that zinc complexes interact with 2,5-pyridinedicarboxyc acid.","PeriodicalId":10648,"journal":{"name":"Communications in Inorganic Synthesis","volume":"57 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2017-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Communications in Inorganic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21060/cis.v5i2.2692","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Abstract: Two new Zn(II) N-(4-X-phenyl)pyridine-2-yl-methanimine complexes, [Zn(NN´-Cl)Cl 2 ]( 1 ) and [Zn(NN´-N(CH 3 ) 2 )Cl 2 ]( 2 ), have been synthesized and characterized by elemental analysis, FT-IR and NMR- 1 H spectra. The crystal structure of complex 1 was determined by X-ray single crystal diffraction. Experiments performed by Benesi-Hilderbrand method indicate that zinc complexes interact with 2,5-pyridinedicarboxyc acid.