Detection of Harmful Chemical Compounds in Plastic Products Using a High‐Sensitivity Photonic Crystal‐Based Sensor

S. Taya, Samer M. Srour, A. Almawgani, A. Hindi, I. Colak, S. Patel
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Abstract

The use of plastics can be dangerous due to the numerous industrial chemicals they contain. Di(2‐ethylhexyl) phthalate (DEHP), bisphenol A (BPA), and bisphenol S (BPS) are three detrimental organic chemicals that are used in the plastic industry. In this work, a highly sensitive photonic crystal (PCL) sensor is theoretically proposed and numerically simulated as a detector for DEHP, BPA, and BPS organic chemicals. The proposed PCL is a 1D that has the structure (GaAs/Si3N4/TiN)N/cavity layer/(GaAs/Si3N4/TiN)N, where N is the number of unit cells (UCs). The DEHP, BPA, and BPS analytes are assumed to be separately infiltrated into the cavity layer between two equal numbers of the UCs. The transmission spectra of the PCL are studied using the transfer matrix (TrMx) technique. The most important performance parameter is sensitivity so we have focused on it. A considerable sensitivity enhancement is obtained by raising the defect layer thickness and incidence angle. High sensitivities of 2350.51, 2168.45, and 2042.08 nm RIU−1 are obtained for DEHP, BPA, and BPS, respectively. In the results obtained, the way can be paved for a simple technique to detect chemical compounds.
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利用高灵敏度光子晶体传感器检测塑料制品中的有害化合物
塑料的使用可能是危险的,因为它们含有大量的工业化学物质。邻苯二甲酸二(2‐乙基己基)酯(DEHP)、双酚A (BPA)和双酚S (BPS)是塑料工业中使用的三种有害的有机化学物质。在这项工作中,从理论上提出了一种高灵敏度的光子晶体(PCL)传感器,并进行了数值模拟,作为DEHP, BPA和BPS有机化学品的探测器。所提出的PCL是具有(GaAs/Si3N4/TiN)N/腔层/(GaAs/Si3N4/TiN)N结构的1D,其中N为单元胞(UCs)的数量。假定DEHP、BPA和BPS分析物分别渗透到两个等量UCs之间的空腔层中。利用传输矩阵(TrMx)技术研究了PCL的透射光谱。最重要的性能参数是灵敏度,所以我们关注它。通过提高缺陷层厚度和入射角,可以显著提高灵敏度。DEHP、BPA和BPS的RIU−1灵敏度分别为2350.51、2168.45和2042.08 nm。在获得的结果中,可以为一种简单的检测化合物的技术铺平道路。
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