{"title":"Antimony-121 Mössbauer spectroscopy of some chloro-complexes of antimony","authors":"T. Birchall, B. Valle, E. Martineau, J. Milne","doi":"10.1039/J19710001855","DOIUrl":null,"url":null,"abstract":"The 121Sb Mossbauer spectra of a number of chloroantimony salts have been examined. The presence of both SbIII and SbV in Rb2SbCl6 is confirmed. Extremely large, negative isomer shifts are obtained for [SbIIICl6]3– species and are interpreted in terms of a stereochemically inactive Ione-pair of electrons.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"9","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710001855","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 9
Abstract
The 121Sb Mossbauer spectra of a number of chloroantimony salts have been examined. The presence of both SbIII and SbV in Rb2SbCl6 is confirmed. Extremely large, negative isomer shifts are obtained for [SbIIICl6]3– species and are interpreted in terms of a stereochemically inactive Ione-pair of electrons.
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