EFFECTS OF PH AND SOLID CONCENTRATION ON THE RHEOLOGY OF DRILLING FLUIDS COMPOSED BY NATURAL CLAY, WATER, AND NaCMC

B. R. Oliveira, R. Oliveira, C. Scheid, A. Ferraz, M. Marques, L. Calçada
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Abstract

The functions of drilling fluids depend directly on the fluid’s physical, chemical, and rheological properties. The selection and control of fluid composition is crucial to obtain the best performance in the process of drilling oil. The presence of solid particulate material and viscosifying agents contributes to the maintenance of the rheological behavior of these fluids. The pH variation during the drilling may affect rheological properties leading to poor well cleaning and drill string imprisonment. This work aims to evaluate the influence of solid concentration and pH variation in the rheological behavior of carboxymethyl cellulose and natural clay dispersions. Results indicated that solid concentration increased the apparent viscosity of dispersions due to chemical interactions between the polymer and the particles of natural clay. Dispersions at a pH lower than five presented lower values of yield stress and apparent viscosity than dispersions with higher pH values. The protonation of the carboxylic groups of the NaCMC resulted in a hydrophobicity increase of NaCMC and in a subsequent reduction of natural clay wettability. The formation of natural clay aggregates caused a decrease in dispersion viscosity.
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PH和固体浓度对天然粘土、水和NaCMC组成的钻井液流变性的影响
钻井液的功能直接取决于其物理、化学和流变性能。在钻井过程中,流体成分的选择和控制是获得最佳性能的关键。固体颗粒材料和增粘剂的存在有助于维持这些流体的流变性能。钻井过程中pH值的变化可能会影响流变性能,导致井清洗不良和钻柱滞留。本工作旨在评价固体浓度和pH变化对羧甲基纤维素和天然粘土分散体流变行为的影响。结果表明,固体浓度增加了分散体的表观粘度,这是由于聚合物与天然粘土颗粒之间的化学相互作用。pH值低于5时,分散体的屈服应力和表观粘度均低于pH值较高的分散体。NaCMC羧基的质子化导致NaCMC的疏水性增加,随后降低了天然粘土的润湿性。天然粘土团聚体的形成使分散粘度降低。
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