Investigation on synthesis of two ammonium based ionic liquids from fatty acids and triethylamine

T. T. Bui, T. Dang, Khun Borin, Thanh Nam Ly, Trung T. Pham, Thanh Xuan Thi Phan, Ngoc Pham-Cong
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Abstract

Two ionic liquids triethylammonium oleate and  triethylammonium stearate were synthesized from fatty acids and triethyl amine using two different methods (one step and three step methods). The yield triethylammonium oleate rearch 68.8-74% (one step method) and 86.3% (three step method) and of triethylammonium stearate rearch 68.7-74.1 (one step method) and 83.5% (three step method). The one step method spends more time but less chemicals and brings higher yield. FT-IR and 1H-NMR spectra of ILs obtained from both method was measured. The results showed that synthesis method doesn’t affect on the structure of the products and ILs obtained from one step method has higher purity.
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脂肪酸和三乙胺合成两种铵基离子液体的研究
以脂肪酸和三乙胺为原料,采用一步法和三步法合成了油酸三乙胺和硬脂酸三乙胺两种离子液体。油酸三乙铵的收率分别为68.8-74%(一步法)和86.3%(三步法),硬脂酸三乙铵的收率分别为68.7-74.1(一步法)和83.5%(三步法)。一步走法耗时多,化学药品少,产量高。测定了两种方法得到的红外光谱和核磁共振光谱。结果表明,合成方法对产物的结构没有影响,一步法得到的il具有较高的纯度。
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