Synthesis and Characterization of Nanosize Polyanthranillic Acid for Solid Polymer Electrolyte

R. Kirupagaran, C. Vedhi
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Abstract

Article history: Received 20 March 2019 Accepted 29 April 2019 Available online 05 June 2019 Conducting polymer of anthranilic acid (PANA) has been synthesized through emulsion polymerization technique. Emulsion polymerization helps in slowing down kinetics of polymerization in comparison to one-phase polymerization and thereby induces formation of monodispersed. Reaction progress of conducting polymer formation is studied by UV–Vis and FTIR spectroscopy. Morphology of PANA is characterized by XRD, TEM, AFM and electrochemical techniques. XRD of conducting polymer depicts the less crystalline nature of polymer with crystallite size of 75 nm. Voltammetry has shown the electroactive nature of PANA. The performance of energy storage devices including pseudocapacitors is evaluated mostly by measuring energy density and power density.
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固体聚合物电解质用纳米聚氨基苯甲酸的合成与表征
文章历史:2019年3月20日收稿2019年4月29日接受2019年6月5日在线提供2019年6月05日通过乳液聚合技术合成了邻氨基苯甲酸(PANA)导电聚合物。与单相聚合相比,乳液聚合有助于减缓聚合动力学,从而诱导单分散聚合物的形成。利用紫外可见光谱和红外光谱研究了导电聚合物形成的反应过程。采用XRD、TEM、AFM和电化学技术对聚丙烯腈的形貌进行了表征。导电聚合物的XRD表征表明,聚合物的结晶度较低,晶粒尺寸为75 nm。伏安法显示了聚丙烯腈的电活性。包括假电容器在内的储能器件的性能评价主要通过测量能量密度和功率密度来实现。
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