{"title":"Reactions of quinolin-8-ol with covalent halides. Part VI. Bis-π-cyclopentadienyldihalides of titanium, zirconium, and hafnium","authors":"J. Charalambous, M. Frazer, W. Newton","doi":"10.1039/J19710002487","DOIUrl":null,"url":null,"abstract":"The complexes halogenocyclopentadienyldiquinolin-8-olatometal(IV), C5H5MXox2(M = Ti, Zr; X = Cl, Br and M = Hf, X = Cl), have been prepared by the direct interaction of quinolin-8-ol (oxH) and dihalogenobis(cyclopentadienyl)metal(IV)[(C5H5)2MX2] in acetonitrile solution at room temperature. Reactions of these complexes with ethanol, with ethoxide, and with hydrogen halides have been studied. I.r. (4000–80 cm.–1), n.m.r., and mass spectra are reported.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":"81 1","pages":"2487-2491"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"10","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710002487","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 10
Abstract
The complexes halogenocyclopentadienyldiquinolin-8-olatometal(IV), C5H5MXox2(M = Ti, Zr; X = Cl, Br and M = Hf, X = Cl), have been prepared by the direct interaction of quinolin-8-ol (oxH) and dihalogenobis(cyclopentadienyl)metal(IV)[(C5H5)2MX2] in acetonitrile solution at room temperature. Reactions of these complexes with ethanol, with ethoxide, and with hydrogen halides have been studied. I.r. (4000–80 cm.–1), n.m.r., and mass spectra are reported.
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