Effect of Different Retanning Agents on Shrinkage Temperature of Leathers

Beena Zehra, Uzma Nadeem, S. Ismail, B. Solangi, Mohammad Kashif Pervez
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Abstract

Retanning of tanned leathers played an important role to raise the shrinkage temperature characteristic and quantum of retanning agents, where crosslinks are formed with the polypeptide chain of the collagen or other reactive available sites of the collagen. This study is useful for the tanners to determine the percentage of shrinkage by using different retannages. The results revealed that the maximum thermal stability (increase in shrinkage temperature 21-25%) has been found in the basic chromium sulphate retanned leather without destruction of physical properties. Beside this, other types of retannages i-e, mineral retanning, phenolic based retanning, formalin based syntan have been showed thermal stability upto different levels (increase in shrinkage temperature 4-6%,12-15%, 10- 14% respectively) in addition to the development of physical properties such as tensile strength (N/ mm2 ), tear strength (N/mm), fullness , etc. to suit different needs.
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不同复鞣剂对皮革收缩温度的影响
鞣革的复鞣对提高复鞣剂的收缩温度特性和收缩量有重要作用,其中复鞣剂与胶原蛋白的多肽链或胶原蛋白的其他活性位点形成交联。本研究为制革企业确定不同复鞣剂的收缩率提供了依据。结果表明,碱式硫酸铬复鞣革在不破坏物理性能的情况下具有最大的热稳定性(收缩温度提高21-25%)。除此之外,其他类型的复鞣剂i-e、矿物复鞣剂、酚醛复鞣剂、福尔马林复鞣剂均表现出不同程度的热稳定性(收缩温度分别增加4-6%、12-15%、10- 14%),以及抗拉强度(N/ mm2)、撕裂强度(N/mm)、填充度等物理性能的发展,以适应不同的需求。
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