Technological evaluation of Pinus maximinoi wood for industrial use in kraft pulp production

M. Coelho, F. DA SILVA, JR., Flaviana Reis Milagres, Silvana Meister Sommer, Carlos Augusto Soares DO AMARAL, Fabricio A Biernaski
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Abstract

This study characterized Pinus maximinoi wood and evaluated its performance for pulp production. Samples of Pinus taeda wood were used as reference material. For both species, wood chips from 14-year-old trees were used for the technological characterization, pulping, bleaching process analysis, and pulp properties. A modified kraft pulping process was carried out targeting kappa number 28±5% on brownstock pulp. The bleaching sequence was applied for bleached pulp with final brightness of 87±1 % ISO. Refinability and resistance properties were measured in the bleached pulps. Compared to P. taeda wood, P. maximinoi showed slightly higher basic density (0.399 g/cm³) and higher holocellulose (64.5%), lignin (31.1%), and extractives content (4.5%), along with lower ash content (0.16%). P. maximinoi tracheids showed greater wall thickness (6.4 µm) when compared to P. taeda tracheids. For the same kappa number, P. maximinoi and P. taeda resulted in similar screened yield, with an advantage observed for P. maximinoi, which resulted in lower specific wood consumption (5.281 m³/o.d. metric ton), and lower black liquor solids (1.613 metric tons/o.d. metric ton). After oxygen delignification, P. maximinoi pulp showed higher efficiency on kappa reduction (67.2%) and similar bleaching chemical demand as P. taeda pulp. Compared to P. taeda pulps, the refined P. maximinoi pulps had similar results and the bulk property was 10% higher. Results showed that P. maximinoi is an interesting alternative raw material for softwood pulp production in Brazil.
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工业用大松木硫酸盐纸浆的工艺评价
本研究对大松木材进行了表征,并对其制浆性能进行了评价。以红松木材为对照品。对这两种木材进行了工艺表征、制浆、漂白过程分析和纸浆性能分析。以褐煤浆为原料,以kappa值为28±5%为目标,进行了改良硫酸盐制浆工艺。采用漂白顺序对漂白浆进行漂白,最终亮度为87±1% ISO。对漂白后的纸浆进行了再精炼性和抗磨性能的测试。与紫檀相比,紫檀的基本密度(0.399 g/cm³)略高,总纤维素(64.5%)、木质素(31.1%)和浸出物含量(4.5%)较高,灰分含量(0.16%)较低。大叶青管胞壁厚为6.4µm,大叶青管胞壁厚为6.4µm。在相同的kappa数下,大叶青和野叶青的筛选产量相似,其中大叶青的优势在于其比木材消耗量较低(5.281 m³/o.d)。吨)和较低的黑色液体固体(1.613公吨/日)。公吨)。经氧脱木质素处理后,最大木质素纸浆的kappa还原效率为67.2%,漂白化学需要量与紫檀纸浆相近。精制后的大黄木浆与大黄木浆具有相似的效果,体积性能提高了10%。结果表明,在巴西,马氏木浆是一种有趣的替代原料。
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