Effect of Sn Addition on Thermal and Optical Properties of Glass

V. Modgil, V. S. Rangra
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引用次数: 19

Abstract

Study of thermal and optical parameters of glass has been undertaken. Crystallization and glass transition kinetics has been investigated under nonisothermal conditions by DSC technique. Phase separation has been observed in the material and is investigated by taking the XRD of annealed bulk samples. The material possesses good glass forming ability, high value of glass transition temperature about 420 K, and glass stability. Optical band gap and other optical constants such as refractive index and extinction coefficient have been determined. The isoelectronic substitution of Ge with Sn in the glassy system reduces the optical band gap and enhances the thermal properties.
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添加锡对玻璃热光学性能的影响
对玻璃的热、光学参数进行了研究。用DSC技术研究了非等温条件下的结晶和玻璃化转变动力学。在材料中观察到相分离现象,并对退火后的样品进行了XRD分析。该材料具有良好的玻璃化成型能力,玻璃化转变温度高达420 K,玻璃化稳定性好。测定了光学带隙和其他光学常数,如折射率和消光系数。在玻璃化体系中,Ge与Sn的等电子取代减小了光学带隙,提高了热性能。
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