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Modification of Aluminium 6063 Microstructure by Adding Boron and Titanium to Improve the Thermal Conductivity 添加硼和钛改性铝6063组织以提高导热性
Pub Date : 2018-01-24 DOI: 10.1155/2018/8905469
M. Shaira, Suleiman Yousef
This study aimed to improve the thermal conductivity of the Aluminium 6063 for heat sinks applications used in Central Processing Unit (CPU) of computers. Several studies had used different additional elements for this goal. In this paper, we studied the influence of Titanium and Boron addition on the thermal conductivity of Aluminium 6063. Several casting alloys samples were prepared with different percentage of addition elements and then heat-treated by homogenization and aging treatments. The results showed an important modification in thermal conductivity value per rapport to the reference metal, depending on the element of addition and its percentage. The bigger evolution was by using Boron in small percentage. More than 13% of the improvement was realized in the thermal conductivity with the addition of only 0.05% of Boron.
本研究旨在改善用于计算机中央处理器(CPU)散热器的铝6063的导热性。有几项研究使用了不同的附加因素来实现这一目标。本文研究了钛和硼的加入对铝6063导热性能的影响。制备了几种添加元素含量不同的铸造合金样品,并对其进行了均匀化和时效处理。结果表明,根据添加元素及其百分比的不同,对参考金属的热导率值有重要的变化。更大的进化是通过使用少量的硼。仅添加0.05%的硼,导热系数就提高了13%以上。
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引用次数: 3
Well-Dispersed Nanoscale Zero-Valent Iron Supported in Macroporous Silica Foams: Synthesis, Characterization, and Performance in Cr(VI) Removal 大孔二氧化硅泡沫中分散良好的纳米级零价铁:合成、表征和去除Cr(VI)的性能
Pub Date : 2017-09-10 DOI: 10.1155/2017/3094606
Chaoxia Zhao, Jie Yang, Yihan Wang, B. Jiang
Well-dispersed nanoscale zero-valent iron (NZVI) supported inside the pores of macroporous silica foams (MOSF) composites (Mx-NZVI) has been prepared as the Cr(VI) adsorbent by simply impregnating the MOSF matrix with ferric chloride, followed by the chemical reduction with NaHB4 in aqueous solution at ambient atmosphere. Through the support of MOSF, the reactivity and stability of NZVI are greatly improved. Transmission electron microscopy (TEM) results show that NZVI particles are spatially well-dispersed with a typical core-shell structure and supported inside MOSF matrix. The N2 adsorption-desorption isotherms demonstrate that the Mx-NZVI composites can maintain the macroporous structure of MOSF and exhibit a considerable high surface area (503 m2·g−1). X-ray photoelectron spectroscopy (XPS) and powder X-ray diffraction (XRD) measurements confirm the core-shell structure of iron nanoparticles composed of a metallic Fe0 core and an Fe(II)/Fe(III) species shell. Batch experiments reveal that the removal efficiency of Cr(VI) can reach 100% when the solution contains 15.0 mg·L−1 of Cr(VI) at room temperature. In addition, the solution pH and the composites dosage can affect the removal efficiency of Cr(VI). The Langmuir isotherm is applicable to describe the removal process. The kinetic studies demonstrate that the removal of Cr(VI) is consistent with pseudo-second-order kinetic model.
在大孔二氧化硅泡沫(MOSF)复合材料(Mx-NZVI)的孔内,通过简单地将三氯化铁浸渍在MOSF基体上,然后在环境气氛下用NaHB4在水溶液中进行化学还原,制备了分散良好的纳米级零价铁(NZVI)作为Cr(VI)吸附剂。通过MOSF的支持,大大提高了NZVI的反应性和稳定性。透射电镜(TEM)结果表明,NZVI颗粒空间分散良好,具有典型的核壳结构,并支撑在MOSF基体内。N2吸附-解吸等温线表明,复合材料能保持MOSF的大孔结构,并具有相当高的比表面积(503 m2·g−1)。x射线光电子能谱(XPS)和粉末x射线衍射(XRD)测量证实了铁纳米粒子的核壳结构,该结构由金属Fe0核和Fe(II)/Fe(III)种壳组成。批量实验表明,室温条件下,当溶液中Cr(VI)的浓度为15.0 mg·L−1时,对Cr(VI)的去除率可达100%。此外,溶液pH和复合材料投加量对Cr(VI)的去除率也有影响。Langmuir等温线适用于描述去除过程。动力学研究表明,Cr(VI)的去除符合准二级动力学模型。
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引用次数: 11
Investigation of Properties of Silk Fiber Produced in Ethiopia 埃塞俄比亚产蚕丝纤维的性能研究
Pub Date : 2017-05-28 DOI: 10.1155/2017/7691797
A. Banale
The atmospheric conditions and other facilities to rear silk filaments are good in Ethiopia. In Awassa, Awash Melkassa, and Kombolcha silk rearing is started with good progress. The quality of the cocoons produced in the country is not determined in relation to commercial silk produced in major silk producing countries. So far there was no information available about the basic properties of silk filaments produced. In this research paper, the different physical properties of the eri and mulberry cocoon and their filaments were evaluated. Eri cocoons have shell ratio of approximately 14%, average fiber fineness of 3 dtex, and average weight of 3.2–3.3 g, while mulberry cocoons have raw silk ratio of 13-14%, average fiber fineness of 2 dtex, and average weight of 1.5 g. Even though the method of rearing, handling, and harvesting of the cocoons is poor, the physical properties of the silk produced in Ethiopia fall within the limits of commercial silk produced in major silk producing countries.
埃塞俄比亚的大气条件和其他设施都很好。在阿瓦萨、阿瓦什梅尔卡萨和康伯尔查,养丝开始取得了良好的进展。该国生产的蚕茧质量与主要产丝国生产的商品蚕丝没有关系。到目前为止,还没有关于生产的丝的基本特性的信息。本文对蚕茧和桑蚕蚕丝的不同物理性质进行了评价。蚕茧的壳比约为14%,平均纤维细度为3 dtex,平均重量为3.2-3.3 g;桑蚕茧的生丝比为13-14%,平均纤维细度为2 dtex,平均重量为1.5 g。尽管饲养、处理和收获蚕茧的方法很差,但埃塞俄比亚生产的蚕丝的物理性能在主要蚕丝生产国生产的商品蚕丝的范围内。
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引用次数: 7
Utilizing Fullerenols as Surfactant for Carbon Nanotubes Dispersions Preparation 富勒烯醇作为表面活性剂制备碳纳米管分散体
Pub Date : 2017-02-23 DOI: 10.1155/2017/4387391
Jianlong Ji, Qiao Chang, L. Yali, Wendong Zhang, S. Sang, Xing Yang, Aoqun Jian, Qianqian Duan, Qiang Zhang, Y. Liu
Dispersions of individual carbon nanotubes (CNTs) are crucial for nanodevices and polymer/CNTs nanocomposites. In this paper, stable and homogenous dispersions of individual multiwalled carbon nanotubes (MWCNTs) have been synthesized. The factors influencing the dispersibility mechanism, including the surfactant concentration and the pH value, have been investigated. SEM images display the impurities sticking on MWCNTs which have been removed. The oxygen-containing groups on the surface of MWCNTs sample have been detected through FT-IR and Raman spectra. All experimental results illustrate that using fullerenols as surfactant can greatly improve the dispersibility of MWCNTs. Moreover, the prepared dispersions exhibit good stability that the sediment percentage of fullerenols-MWCNTs is only 5.2% after 5 days.
单个碳纳米管(CNTs)的分散对于纳米器件和聚合物/CNTs纳米复合材料至关重要。本文合成了稳定且均匀分散的单个多壁碳纳米管(MWCNTs)。考察了表面活性剂浓度和pH值等因素对分散性机理的影响。SEM图像显示杂质粘附在已去除的MWCNTs上。利用红外光谱和拉曼光谱对MWCNTs样品表面的含氧基团进行了检测。实验结果表明,富勒烯醇作为表面活性剂可以显著提高MWCNTs的分散性。此外,制备的分散体具有良好的稳定性,5天后富勒烯- mwcnts的沉淀率仅为5.2%。
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引用次数: 2
Preparation, Characterization, and Cationic Functionalization of Cellulose-Based Aerogels for Wastewater Clarification 纤维素基气凝胶用于废水澄清的制备、表征和阳离子功能化
Pub Date : 2016-12-20 DOI: 10.1155/2016/3186589
Yang Hu, Shanshan Li, Tanya Jackson, H. Moussa, N. Abidi
Aerogels are a series of materials with porous structure and light weight which can be applied to many industrial divisions as insulators, sensors, absorbents, and cushions. In this study, cellulose-based aerogels (aerocelluloses) were prepared from cellulosic material (microcrystalline cellulose) in sodium hydroxide/water solvent system followed by supercritical drying operation. The average specific surface area of aerocelluloses was 124 m2/g. The nitrogen gas (N2) adsorption/desorption isotherms revealed type H1 hysteresis loops for aerocelluloses, suggesting that aerocelluloses may possess a porous structure with cylindrically shaped pores open on both ends. FTIR and XRD analyses showed that the crystallinity of aerocelluloses was significantly decreased as compared to microcrystalline cellulose and that aerocelluloses exhibited a crystalline structure of cellulose II as compared to microcrystalline cellulose (cellulose I). To perform cationic functionalization, a cationic agent, (3-chloro-2-hydroxypropyl) trimethylammonium chloride, was used to introduce positively charged sites on aerocelluloses. The cationized aerocelluloses exhibited a strong ability to remove anionic dyes from wastewater. Highly porous and low cost aerocelluloses prepared in this study would be also promising as a fast absorbent for environmental pollutants.
气凝胶是一系列具有多孔结构和轻质的材料,可作为绝缘体、传感器、吸附剂和缓冲材料应用于许多工业部门。以纤维素材料(微晶纤维素)为原料,在氢氧化钠/水溶剂体系中进行超临界干燥,制备纤维素基气凝胶(气凝胶)。航空纤维素的平均比表面积为124 m2/g。氮气吸附/解吸等温线显示了航空纤维素的H1型滞后环,表明航空纤维素可能具有两端开放圆柱状孔的多孔结构。FTIR和XRD分析表明,与微晶纤维素相比,航空纤维素的结晶度明显降低,并且与微晶纤维素(纤维素I)相比,航空纤维素具有纤维素II的晶体结构。为了实现阳离子功能化,使用阳离子剂(3-氯-2-羟丙基)三甲基氯化铵在航空纤维素上引入正电荷位点。阳离子化后的航空纤维素对废水中的阴离子染料具有较强的去除能力。本研究制备的高孔低成本航空纤维素也有望成为环境污染物的快速吸收剂。
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引用次数: 24
Superplastic Grade Titanium Alloy: Comparative Evaluation of Mechanical Properties, Microstructure, and Fracture Behavior 超塑性级钛合金:力学性能、显微组织和断裂行为的比较评价
Pub Date : 2016-12-05 DOI: 10.1155/2016/2309232
K. Sudhakar, E. Wood
In this investigation, static fracture, microstructure, and the mechanical behavior of SP-700 alloy (a superplastic grade) were evaluated and compared with two other titanium alloys. The comparisons were made in terms of suitably designed heat treatment cycles. The heat treatment cycles included annealing and a combination of solutionizing and aging treatments for all three alloys. Tensile properties were determined using MTS Landmark Servohydraulic Test System. Tensile tested samples’ fracture surfaces were investigated with LEO-VP SEM instrument. Ti-15-3-3-3 alloy exhibited relatively a higher combination of strength and ductility in comparison to the other two alloys. All three types of titanium alloys demonstrated a very good level of tensile strength and ductility suitable for applications in military and biomedical fields.
在本研究中,对SP-700合金(超塑性等级)的静态断口、显微组织和力学行为进行了评价,并与其他两种钛合金进行了比较。在适当设计热处理循环方面进行了比较。热处理循环包括退火和三种合金的固溶和时效处理的组合。拉伸性能采用MTS Landmark伺服液压测试系统进行测试。用LEO-VP扫描电镜对拉伸试样的断口形貌进行了研究。与其他两种合金相比,Ti-15-3-3-3合金表现出相对较高的强度和塑性组合。所有三种类型的钛合金都表现出非常好的抗拉强度和延展性,适用于军事和生物医学领域的应用。
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引用次数: 7
Synthesis and Characteristics of Valeric Acid-Zinc Layered Hydroxide Intercalation Material for Insect Pheromone Controlled Release Formulation 昆虫信息素控释剂中戊酸-锌层状氢氧化物插层材料的合成及性能研究
Pub Date : 2016-10-25 DOI: 10.1155/2016/1285721
R. Ahmad, M. Hussein, S. H. Sarijo, W. Kadir, T. Y. Hin
A new intercalation compound of insect pheromone, valeric acid (VA), based on zinc layered hydroxide (ZLH) as host release material, was successfully prepared through coprecipitation method. The as-produced organic-inorganic nanolayered material, valerate nanohybrid, VAN, shows the formation of a new peak at lower 2θ angle with basal spacing of 19.8 A with no ZnO reflections, which indicate that the intercalation of anion between the inorganic ZLH interlamellae was accomplished. The elemental, FTIR, and ATR analyses of the nanohybrid supported the fact that the intercalation with the percentage anion loading was calculated to be 23.0% (w/w). The thermal stability property of the resulting nanohybrid was enhanced compared to the unbound anion. Field emission scanning electron micrograph of the ZnO has a nonuniform granular structure but transforms into flake-like structure with various sizes after the intercalation process. Release kinetics of anion from the interlayer of intercalated compound exhibited a slow release behavior governed by the pseudo-second-order kinetic model at different pHs of aqueous media. The valerate anion was released from VAN with the highest release rate at pH 4. These findings provide the basis to further development of controlled release formulation for insect pheromone based on ZLH intercalation.
以层状氢氧化锌(ZLH)为寄主释放材料,采用共沉淀法成功制备了一种新的昆虫信息素插层化合物——戊酸(VA)。制备的有机-无机纳米层材料valerate nanohybrid, VAN在2θ角下形成了一个基底间距为19.8 a的新峰,没有ZnO反射,这表明在无机ZLH层间完成了阴离子的插层。元素、FTIR和ATR分析支持这样一个事实,即负离子负载的插层率为23.0% (w/w)。与未结合的阴离子相比,所得到的纳米杂化物的热稳定性得到了增强。ZnO在场发射扫描电镜下具有不均匀的粒状结构,经过插层处理后转变为大小不一的片状结构。在不同ph的水介质中,阴离子从插层化合物的释放动力学表现为准二级动力学模型控制的缓释行为。在pH为4时,戊酸盐阴离子从VAN中释放出来,释放率最高。研究结果为进一步开发基于ZLH插层的昆虫信息素控释制剂提供了依据。
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引用次数: 8
A Novel Hysteresis Model of Magnetic Field Strength Determined by Magnetic Induction Intensity for Fe-3% Si Electrical Steel Applied in Cigarette Making Machines 卷烟机械用Fe-3% Si电工钢磁感应强度决定磁场强度的磁滞模型
Pub Date : 2016-10-18 DOI: 10.1155/2016/1509498
W. Hao, Jianbo Zhan, Zhenhua Yu, Zhang Ying, Jiang Yu, Gui Yongfa, Yuan Tingting, Xie Jiao, Hongkui Zhang, Ya-feng Ji, N. Zan, Rongrong Fu, Deniz Perin
Hysteresis characteristics of grain-oriented electrical steel were studied through the hysteresis loop. Existing hysteresis fitting simulation methods were summarized, and new Fe-3% Si grain-oriented electrical steel hysteresis loop model was proposed. Undetermined coefficients of the magnetic field intensity and magnetic flux density were determined by both the fixed angle method and the least squares method, and the hysteresis loop model was validated with high fitting degree by experimental data.
通过磁滞回线研究了晶粒取向电工钢的磁滞特性。总结了现有的迟滞拟合仿真方法,提出了新的Fe-3% Si取向电钢迟滞回线模型。采用定角法和最小二乘法确定了磁场强度和磁通密度的待定系数,并通过实验数据验证了磁滞回线模型具有较高的拟合度。
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引用次数: 1
Fabrication and Microhardness Analysis of MWCNT/MnO2 Nanocomposite MWCNT/MnO2纳米复合材料的制备及显微硬度分析
Pub Date : 2016-10-10 DOI: 10.1155/2016/6070468
M. Z. Hussain, Sabah Khan, R. Nagarajan, Urfi Khan, V. Vats
Recent research has shown that carbon nanotube (CNT) acts as a model reinforcement material for fabricating nanocomposites. The addition of CNT as a reinforcing material into the matrix improves the mechanical, thermal, tribological, and electrical properties. In this research paper multiwalled carbon nanotube (MWCNT), with different weight percentage (5%, 10%, and 15%), was reinforced into manganese dioxide (MnO2) matrix using solution method. The different weight % of MWCNT/MnO2 nanocomposite powders was compacted and then sintered. The phase analysis, morphology, and chemical composition of the nanocomposites were examined by X-ray diffractometer, Field Emission Scanning Electron Microscope (FESEM), and Energy Dispersive X-Ray (EDX), respectively. The XRD analysis indicates the formation of MWCNT/MnO2 nanocomposites. The FESEM surface morphology analysis shows that MnO2 nanotube is densely grown on the surface of MWCNT. Further, microhardness of MWCNT/MnO2 nanocomposite was measured and it was found that 10 wt% has higher microhardness in comparison to 5 and 15 wt%. The microhardness of the composites is influenced by mass density, nanotube weight fraction, arrangement of tubes, and dispersion of MWCNT in H2SO4(aq) solution.
近年来的研究表明,碳纳米管(CNT)是制备纳米复合材料的一种模型增强材料。在基体中加入碳纳米管作为增强材料,提高了机械、热、摩擦学和电学性能。本研究采用溶液法将不同重量百分比(5%、10%和15%)的多壁碳纳米管(MWCNT)增强到二氧化锰(MnO2)基体中。将不同重量%的MWCNT/MnO2纳米复合粉体压实后烧结。采用x射线衍射仪、场发射扫描电镜(FESEM)和能量色散x射线(EDX)对纳米复合材料的物相分析、形貌和化学成分进行了表征。XRD分析表明形成了MWCNT/MnO2纳米复合材料。FESEM表面形貌分析表明,MnO2纳米管密集生长在MWCNT表面。此外,测量了MWCNT/MnO2纳米复合材料的显微硬度,发现10 wt%的MWCNT/MnO2纳米复合材料的显微硬度高于5 wt%和15 wt%。复合材料的显微硬度受质量密度、纳米管质量分数、纳米管排列和纳米管在H2SO4(aq)溶液中的分散程度的影响。
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引用次数: 15
Analysis of Depth of Shade on Mercerized and Unmercerized Fabric among Different Woven Fabric Structures 不同机织织物结构对丝光和未丝光织物遮光深度的影响分析
Pub Date : 2016-10-10 DOI: 10.1155/2016/9739380
Shamim Alam
The main objective of this paper is to analyze and compare the color strengths of mercerized and unmercerized fabric among different fabric structures. In this research work Remazol reactive dye and three types of woven fabrics were used such as sheeting, sheeting, and herringbone. Spectrophotometer was used to find out the amount of dye which is fixed in the fabrics after soap wash. Three different woven fabrics were dyed with reactive dye (Remazol Red, Remazol Yellow, and Remazol Blue) using pad dyeing method. It was found that mercerized fabric had higher depth of shade under the same dye concentration. In case of shade A (0.5%) sheeting showed better color strength compared to other two structures but for shade B (1.5%) and shade C (4%) herringbone fabric showed better dye absorptive capacity than sheeting.
本文的主要目的是分析和比较不同织物结构的丝光和未丝光织物的色强。本研究以雷玛佐活性染料为原料,采用三种机织物,分别为片布、片布和人字布。用分光光度计测定皂洗后织物上固定的染料量。用活性染料(雷马佐红、雷马佐黄、雷马佐蓝)轧染法对三种不同的机织物进行染色。结果表明,在相同的染料浓度下,丝光织物具有较高的色度。在色度A(0.5%)的情况下,人字织物比其他两种结构表现出更好的色强,但在色度B(1.5%)和色度C(4%)的情况下,人字织物比人字织物表现出更好的染料吸收能力。
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引用次数: 2
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Journal: Materials
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