A Study on Tetraphenylporphyrin as a Corrosion Inhibitor for Pure Magnesium

Junying Hu, Daobing Huang, Guoan Zhang, G. Song, Xingpeng Guo
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引用次数: 11

Abstract

Summary Thesynthesizedenvironment-friendlytetraphenylporphyrin(TPP)proved to be an efficient inhibitor for pure Mg. TPP may chelate withMgandformaTPP-Mgcompound,precipitatingonMgsurface.ThismeansthatTPPanditsderivativemayactaseffectiveinhibitorsforMgalloys; chelating reaction could be a mechanism responsible for Mgcorrosion inhibition. Following this, more highly efficient inhibitorsmay be identified for Mg alloys. Acknowledgments The authors thank the support of the Center of Forecasting andAnalysis,HuazhongUniversityofScienceandTechnology,inmolec-ular simulation. References 1. E. Ghali, “Magneisum and Magnesium alloys,” Uhlig’s Corrosion Handbook : 793(2000).2. G. Song and D. StJohn, Mater. Corros. , 56 ,15 (2005).3. G.-L. Song and Z. Xu, Electrochim. Acta. , 55 , 4148 (2010).4. L.J.Li,Z.M.Yao,J.L.Lei,H.Xu,S.T.Zhang,andF.S.Pan, Acta.Physico-Chimica.Sinica. , 25 , 1332 (2009).5. J. L. Lei, L. J. Li, H. S. Yu, M. L. Chen, S. T. Zhang, and F. S. Pan, Chem Res &Appl , 20 , 461 (2008).6. E. Slavcheva and G. Schmitt,
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四苯基卟啉作为纯镁缓蚀剂的研究
合成的环境友好型四苯基卟啉(TPP)是一种高效的纯Mg抑制剂。TPP可以与mg和形成pp - mg化合物螯合,在mg表面沉淀,这意味着ppp及其衍生物可以作为有效的抑制剂。螯合反应可能是抑制镁腐蚀的一种机制。在此之后,可能会发现更高效的Mg合金缓蚀剂。作者感谢华中科技大学预测与分析中心在分子模拟方面的支持。引用1。E. Ghali,“镁和镁合金”,Uhlig腐蚀手册:793(2000)。脱线,G.宋和D.约翰。Corros。, 56,15 (2005). 2G.-L。宋、许之,电化学。学报。[3]中国生物医学工程学报,2010,41(4)。L.J.Li、Z.M.Yao J.L.Lei、H.Xu S.T.Zhang andF.S。锅,Acta.Physico-Chimica.Sinica。中国生物医学工程学报,25,1332(2009).5。6.雷建林,李丽娟,于洪生,陈明林,张树涛,潘凤生,化学研究与应用,20,461(2008)。E. Slavcheva和G. Schmitt,
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来源期刊
Electrochemical and Solid State Letters
Electrochemical and Solid State Letters 工程技术-材料科学:综合
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