New Quasi-One-Dimensional Organic-Inorganic Hybrid Material: 1,3-Bis(4-piperidinium)propane Pentachlorobismuthate(III) Synthesis, Crystal Structure, and Spectroscopic Studies

H. Ferjani, H. Boughzala
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引用次数: 9

Abstract

The organic-inorganic hybrid compound (C13H28N2) BiCl5 was synthesized by solvothermal method. The crystal structure was solved by single-crystal X-ray diffraction. The compound crystallizes in the orthorhombic system space group Cmc21 with (4) A, (6) A, (3) A, and . The crystal structure was refined down to . It consists of corrugated layers of [BiCl5]2− chains, separated by organic [H2TMDP]2
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新型准一维有机-无机杂化材料:1,3-双(4-哌啶)丙烷五氯双酸盐(III)的合成、晶体结构和光谱研究
采用溶剂热法合成了有机无机杂化化合物(C13H28N2) BiCl5。用单晶x射线衍射分析了晶体结构。该化合物与(4)A、(6)A、(3)A、和在正交系空间群Cmc21中结晶。晶体结构被细化到。它由[BiCl5]2−链的波纹层组成,由有机[H2TMDP]2隔开
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