Study on Dispersion Characteristics of FK5112 Mixed with Inert Gas

Haoran Xing, Song Lu, N. Tao, Rulin Liu
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引用次数: 1

Abstract

New clean agent fire suppressant, Perfluoro-2-methyl-3-pentanone, also known as FK5112 or Novec 1230 has excellent environmental behavior and high efficiency, and has been considered as one of the most promising halon replacement extinguishing agents. However, its high boiling point and poor dispersibility has largely restricted further application. To address the issue, our present work proposes the novel method by introducing inert gas mixed with FK5112 to improve the agent dispersibility. The evaporation mechanism of FK5112 during the mixing has been demonstrated in detail, and the droplets evaporation time of FK5112 affected by the diameter, the partial pressure of vapor, and the diffusion coefficient of different inert gas is estimated. Our results show that the droplets size of FK5112 have significant effect on evaporation, as it takes only 0.076s for a 5µm droplet to completely evaporate in N2 even if the partial pressure is high(a=80%). After FK5112 has evaporated in the inert gas, dispersion properties of the binary agent have been calculated and discussed thoroughly. The precise equation to estimate the vapor pressure of FK5112 is selected and the relation with the boiling point, mixing ratio, and pressure of the binary agent is revealed. For the 20% mixing ratio of FK5112, the boiling point of the mixture can reach 8.49°C and for the 10% mixing ratio, the boiling temperature is -5.85°C, which shows mixing with inert gas could notably improve its dispersibility. Additionally, mixing ratio and droplets size of FK5112 have shown a great impact.
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FK5112与惰性气体混合的分散特性研究
新型清洁灭火剂全氟-2-甲基-3-戊酮,又称FK5112或Novec 1230,具有优异的环保性能和高效能,被认为是最有前途的哈龙替代灭火剂之一。但其沸点高,分散性差,在很大程度上制约了其进一步应用。为了解决这一问题,本文提出了引入惰性气体与FK5112混合的新方法,以提高药剂的分散性。详细论证了FK5112在混合过程中的蒸发机理,并估计了FK5112液滴的蒸发时间受直径、蒸汽分压和不同惰性气体扩散系数的影响。结果表明,FK5112液滴大小对蒸发有显著影响,即使分压很高(a=80%), 5µm液滴在N2中完全蒸发只需要0.076s。对FK5112在惰性气体中蒸发后的分散性能进行了计算和讨论。选择了精确估算FK5112蒸汽压的公式,揭示了其与沸点、混合比和二元剂压力的关系。当FK5112的混合比例为20%时,混合物的沸点可达8.49℃,当FK5112的混合比例为10%时,混合物的沸点为-5.85℃,说明与惰性气体的混合可显著提高其分散性。此外,FK5112的混合比和液滴大小也表现出很大的影响。
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