preparation of palladium Catalyst from bauxite ore and using for kerosene treatment

W. Saeed, Qaidar Salim
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Abstract

The research was aimed to used bauxite ore that has a high aluminum minerals which available in AlHussainiyat near al-Anbar district as a source of alumina which it used as a catalyst support after being loaded with palladium metal , The components of both bauxite ore and prepared catalyst were studied by X-ray diffraction and fluorescence as well as thermogravimetric analysis (TGA) of the prepared catalyst , After this the catalyst was used in the treatment of kerosene which is distilled at (150-260C) under different conditions of the (temperature , reaction time and the ratio of catalyst) to know the optimal reaction conditions that determid by measuring the (FTIR) and chemical analysis. The optimal conditions: temperature was (250C), reaction time was (2hours) and the catalyst ratio was (2%) .The catalyst appeard the ability to dehydrogenation reaction and reforming to form olefinic and aromatic compounds. The research also included the study of n-paraffins separated from kerosene samples that were treating in different temperatures (150,200,250C ) using (HNMR).The results showed the ability of the catalyst towards catalytic cracking and converting n-paraffins to iso-paraffins .
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铝土矿制备钯催化剂及其在煤油处理中的应用
本研究的目的是利用al-Anbar地区附近AlHussainiyat的高铝矿物铝土矿作为氧化铝的来源,并在负载钯金属后用作催化剂载体。用x射线衍射和荧光以及热重分析(TGA)研究了铝土矿和制备的催化剂的成分。然后将催化剂用于处理(150 ~ 260℃)蒸馏煤油,在不同的(温度、反应时间和催化剂配比)条件下,通过红外光谱(FTIR)测量和化学分析确定最佳反应条件。最佳反应条件为温度(250℃)、反应时间(2h)、催化剂配比(2%),催化剂表现出脱氢反应和重整生成烯烃和芳香族化合物的能力。该研究还包括从煤油样品中分离出的正石蜡的研究,这些煤油样品在不同的温度(150、200、250℃)下使用核磁共振(HNMR)进行处理。结果表明,该催化剂具有催化裂解和正石蜡制异石蜡的能力。
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