Towards one-pot selective synthesis of cyclic oligosaccharides.

Toshiki Nokami
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引用次数: 0

Abstract

In this chapter are described electrochemical routes to cyclic oligosaccharides. While automated electrochemical methods have been used to prepare linear oligosaccharides, their conversion to cyclic oligosaccharides proved to be a complex process. The concept of polyglycosylation offers an interesting alternative, and the process which has been developed is that of a one-pot electrochemical polyglycosylation-isomerization-cyclization (ePIC) process.

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环低聚糖的一锅选择性合成。
在这一章描述了电化学途径环状低聚糖。虽然自动化电化学方法已被用于制备线性低聚糖,但将其转化为环状低聚糖是一个复杂的过程。多糖基化的概念提供了一种有趣的替代方法,已经开发的过程是一锅电化学多糖基化-异构化-环化(ePIC)过程。
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来源期刊
Advances in carbohydrate chemistry and biochemistry
Advances in carbohydrate chemistry and biochemistry 生物-生化与分子生物学
CiteScore
2.20
自引率
0.00%
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0
期刊介绍: Advances in Carbohydrate Chemistry and Biochemistry has provided, since its inception in 1945, critical and informative articles written by research specialists that integrate the industrial, analytical, and technological aspects of biochemistry, organic chemistry, and instrumentation methodology to the study of carbohydrates. Its articles present a definitive interpretation of the current status and future trends in carbohydrate chemistry and biochemistry.
期刊最新文献
Towards one-pot selective synthesis of cyclic oligosaccharides. Pseudo-glycoconjugates with a C-glycoside linkage. Conformationally restricted donors for stereoselective glycosylation. Boron-mediated aglycon delivery (BMAD) for the stereoselective synthesis of 1,2-cis glycosides. Therapeutic in vivo synthetic chemistry using an artificial metalloenzyme with glycosylated human serum albumin.
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