UV and Thermal Cure Epoxy Adhesives

Q4 Materials Science Paint and Coatings Industry Pub Date : 2018-11-16 DOI:10.5772/INTECHOPEN.82168
Chunfu Chen, Bin Li, Chao Wang, S. Iwasaki, M. Kanari, D. Lu
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引用次数: 5

Abstract

Typical commercial UV and thermal cure epoxy adhesives have been reviewed and com- pared. UV cure cationic epoxy adhesives are primarily composed of cycloaliphatic epoxy resin and cationic photoinitiator. UV cationic epoxy adhesives have no surface cure issue and possess low cure shrinkage and good adhesion performance but need post-thermal cure to achieve full adhesion performance in use. Hybrid UV acrylate and thermal cure epoxy adhesives are primarily composed of acrylate monomer, free radical photoinitiator, epoxy resin and curing agent. The hybrid epoxy adhesives combine fast UV curability of acrylate composition and high adhesion performance of thermal cure epoxy composition. A new type initiator free hybrid one-component UV and thermal cure adhesive has been also introduced. It is mainly composed of maleimide compound, acrylic monomer, partially acrylated epoxy resin, epoxy resin and latent curing agent. Its UV cure and thermal cure behaviour have been studied by FT-IR spectroscopy measurement.
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UV和热固化环氧胶粘剂
对典型的商用UV和热固化环氧胶粘剂进行了综述和比较。紫外光固化阳离子环氧胶粘剂主要由环脂肪族环氧树脂和阳离子光引发剂组成。UV阳离子环氧胶粘剂没有表面固化问题,固化收缩率低,粘接性能好,但在使用中需要经过热固化才能达到充分的粘接性能。混合UV丙烯酸酯和热固化环氧胶粘剂主要由丙烯酸酯单体、自由基光引发剂、环氧树脂和固化剂组成。混合环氧胶粘剂结合了丙烯酸酯成分的快速UV固化性能和热固化环氧成分的高粘附性能。介绍了一种新型无引发剂单组分UV -热固化复合胶粘剂。它主要由马来酰亚胺化合物、丙烯酸单体、部分丙烯酸化环氧树脂、环氧树脂和潜固化剂组成。通过红外光谱测试研究了其紫外固化和热固化性能。
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Paint and Coatings Industry
Paint and Coatings Industry Business, Management and Accounting-Marketing
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