Durability and wettability of varnishes on the modified and aged surfaces of short rotation teak wood

E. Basri, Resa Martha, R. Damayanti, I. Rahayu, W. Darmawan, P. Gérardin
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引用次数: 1

Abstract

Purpose The surface characteristics of thermally and chemically modified wood, such as surface roughness, surface free energy (SFE) and wettability, are important properties that influence further manufacturing processes such as gluing and coating. The aim of this paper was to determine the influence of the surface roughness of thermally and chemically modified teak wood on their SFE, wettability and bonding quality for water-based acrylic and solvent-based alkyd varnishes. In addition, durability against subterranean termites in the field of these modified teak woods was also investigated to give a valuable information for their further application. Design/methodology/approach The woods tested in this study were fast-growing teak woods that were prepared in untreated and treated with furfuryl alcohol (FA), glycerol maleic anhydride (GMA) and thermal. SFE values were calculated using the Rabel method. The wettability values were measured based on the contact angle between varnish liquids and wood surfaces using the sessile drop method, and the Shi and Gardner model model was used to evaluate the wettability of the varnishes on the wood surface. The bonding quality of the varnishes was measured using a cross-cut test based on ASTM 3359-17 standard. In addition, durability against subterranean termites in the field of these modified teak woods was also investigated according to ASTM D 1758-06. Findings The results showed that furfurylated and GMA-thermal 220°C improved the durability of teak wood against termites. The furfurylated teak wood had the roughest surface with an arithmetic average roughness (Ra) value of 15.65 µm before aging and 27.11 µm after aging. The GMA-thermal 220°C treated teak wood was the smoothest surface with Ra value of 6.44 µm before aging and 13.75 µm after aging. Untreated teak wood had the highest SFE value of 46.90 and 57.37 mJ/m2 before and after aging, respectively. The K values of untreated and treated teak wood increased owing to the aging treatment. The K values for the water-based acrylic varnish were lower than that of the solvent-based alkyd varnish. The untreated teak wood with the highest SFE produced the highest bonding quality (grades 4–5) for both acrylic and alkyd varnishes. The solvent-based alkyd varnish was more wettable and generated better bonding quality than the water-based acrylic varnish. Originality/value The originality of this research work is that it provides evaluation values of the durability and SFE. The SFE value can be used to quantitatively determine the wettability of paint liquids on the surface of wood and its varnish bonding quality.
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短旋柚木改性和老化表面清漆的耐久性和润湿性
目的:热改性和化学改性木材的表面特性,如表面粗糙度、表面自由能(SFE)和润湿性,是影响粘合和涂层等进一步制造过程的重要特性。研究了热改性和化学改性柚木的表面粗糙度对水性丙烯酸清漆和溶剂型醇酸清漆的SFE、润湿性和粘接质量的影响。此外,还研究了改性柚木对地下白蚁的耐久性能,为改性柚木的进一步应用提供了有价值的信息。设计/方法/方法本研究中测试的木材是未经处理的速生柚木,分别用糠醇(FA)、丙三醇马来酸酐(GMA)和热处理。采用Rabel法计算SFE值。采用固滴法根据清漆液与木材表面的接触角测量润湿性,采用Shi和Gardner模型模型评价清漆液对木材表面的润湿性。使用基于ASTM 3359-17标准的横切测试来测量清漆的粘合质量。此外,还根据ASTM D 1758-06对改性柚木的耐久性进行了研究。结果表明,糠化处理和gma -热220℃处理可提高柚木的抗白蚁性能。糠化柚木的表面最粗糙,老化前的算术平均粗糙度(Ra)值为15.65µm,老化后的Ra值为27.11µm。220℃gma热处理的柚木表面最光滑,老化前Ra值为6.44µm,老化后Ra值为13.75µm。未经处理的柚木在老化前和老化后的SFE值最高,分别为46.90和57.37 mJ/m2。未处理和处理过的柚木K值均因老化处理而增大。水性丙烯酸清漆的K值低于溶剂型醇酸清漆。SFE最高的未经处理的柚木对丙烯酸和醇酸清漆的粘接质量最高(4-5级)。溶剂型醇酸清漆比水性丙烯酸清漆具有更好的可湿性和粘接质量。独创性/价值本研究工作的独创性在于提供了耐久性和SFE的评价值。SFE值可定量测定漆液在木材表面的润湿性及其清漆粘接质量。
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