{"title":"Anionic Polymerization in Trimethylamine with Some Alkali Metals","authors":"Y. Hata, Tadashi Yamaguchi","doi":"10.1246/NIKKASHI1898.73.11_2491","DOIUrl":null,"url":null,"abstract":"トリメチルアミン中において触媒にアルカリ金属を用いてスチレンおよびメタクリル酸メチルの重合を行なった。重合速度は触媒量,モノマー濃度の一次に比例する。また重合速度はスチレンではNa=K>Li,メタクリル酸メチルではNa>K>Liの順で減少する。スチレンの場合,その全活性化エネルギーはLi,Na,Kでそれぞれ8.6,4.6,3.3kcal/molであった。","PeriodicalId":22880,"journal":{"name":"The Journal of the Society of Chemical Industry, Japan","volume":"75 ","pages":"2491-2494"},"PeriodicalIF":0.0000,"publicationDate":"1970-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Journal of the Society of Chemical Industry, Japan","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1246/NIKKASHI1898.73.11_2491","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}