{"title":"用于高能量和功率密度混合液流电池的多电子水溶液","authors":"Qiuhong Wang, Walid A. Daoud","doi":"10.1016/j.powera.2020.100018","DOIUrl":null,"url":null,"abstract":"<div><p>Flow battery is a promising energy storage technology for facilitating utilization of renewable resources. While new types of flow batteries have been explored toward high energy density, hampering the power density due to high electrolyte viscosity and sluggish reaction kinetics. Discovery of an aqueous electrolyte with multi-electron transfer reaction is thus favorable for both high energy and power densities due to its multiple charge stored at the same concentration. Both criteria are crucial to improve the flexibility of cell design and widen the application potential. Herein, bismuth is pioneered as negative electrolyte (negolyte) for hybrid flow battery owing to its three-electron reaction and the significantly increased solubility in methanesulfonic acid. In conjunction with cerium electrolyte, a volumetric energy density of 90 Wh L<sup>−1</sup> is achieved and simultaneously a high power density of 295 mW cm<sup>−2</sup> at 90% state-of-charge is demonstrated using low-cost carbon electrode. Furthermore, a high volumetric capacity of 120 Ah L<sup>−1</sup> is reached via adopting graphite felt, which is 100% of the theoretical specific capacity of 1.5 M bismuth negolyte.</p></div>","PeriodicalId":34318,"journal":{"name":"Journal of Power Sources Advances","volume":null,"pages":null},"PeriodicalIF":5.4000,"publicationDate":"2020-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.powera.2020.100018","citationCount":"4","resultStr":"{\"title\":\"Aqueous multi-electron electrolyte for hybrid flow batteries with high energy and power densities\",\"authors\":\"Qiuhong Wang, Walid A. Daoud\",\"doi\":\"10.1016/j.powera.2020.100018\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Flow battery is a promising energy storage technology for facilitating utilization of renewable resources. While new types of flow batteries have been explored toward high energy density, hampering the power density due to high electrolyte viscosity and sluggish reaction kinetics. Discovery of an aqueous electrolyte with multi-electron transfer reaction is thus favorable for both high energy and power densities due to its multiple charge stored at the same concentration. Both criteria are crucial to improve the flexibility of cell design and widen the application potential. Herein, bismuth is pioneered as negative electrolyte (negolyte) for hybrid flow battery owing to its three-electron reaction and the significantly increased solubility in methanesulfonic acid. In conjunction with cerium electrolyte, a volumetric energy density of 90 Wh L<sup>−1</sup> is achieved and simultaneously a high power density of 295 mW cm<sup>−2</sup> at 90% state-of-charge is demonstrated using low-cost carbon electrode. Furthermore, a high volumetric capacity of 120 Ah L<sup>−1</sup> is reached via adopting graphite felt, which is 100% of the theoretical specific capacity of 1.5 M bismuth negolyte.</p></div>\",\"PeriodicalId\":34318,\"journal\":{\"name\":\"Journal of Power Sources Advances\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.4000,\"publicationDate\":\"2020-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/j.powera.2020.100018\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Power Sources Advances\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666248520300184\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Power Sources Advances","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666248520300184","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Aqueous multi-electron electrolyte for hybrid flow batteries with high energy and power densities
Flow battery is a promising energy storage technology for facilitating utilization of renewable resources. While new types of flow batteries have been explored toward high energy density, hampering the power density due to high electrolyte viscosity and sluggish reaction kinetics. Discovery of an aqueous electrolyte with multi-electron transfer reaction is thus favorable for both high energy and power densities due to its multiple charge stored at the same concentration. Both criteria are crucial to improve the flexibility of cell design and widen the application potential. Herein, bismuth is pioneered as negative electrolyte (negolyte) for hybrid flow battery owing to its three-electron reaction and the significantly increased solubility in methanesulfonic acid. In conjunction with cerium electrolyte, a volumetric energy density of 90 Wh L−1 is achieved and simultaneously a high power density of 295 mW cm−2 at 90% state-of-charge is demonstrated using low-cost carbon electrode. Furthermore, a high volumetric capacity of 120 Ah L−1 is reached via adopting graphite felt, which is 100% of the theoretical specific capacity of 1.5 M bismuth negolyte.