{"title":"水的Rydberg光谱的旋转分析","authors":"M. Child, R. D. Gilbert, C. Jungen","doi":"10.1155/LC.11.253","DOIUrl":null,"url":null,"abstract":"Two techniques for rotational analysis of the nd←1b1 Rydberg spectra of H2O and D2O are discussed—a \nCoriolis coupled asymmetric top model for the room temperature 3d←1b1 cluster, and an extension of \nmultichannel quantum defect theory to asymmetric tops, which is applied to recent jet cooled photoionization \nspectra of the nd←1b1 series converging to the (100) vibrational levels of H2O","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"39 10","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Rotational Analysis of the Rydberg Spectrum of Water\",\"authors\":\"M. Child, R. D. Gilbert, C. Jungen\",\"doi\":\"10.1155/LC.11.253\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Two techniques for rotational analysis of the nd←1b1 Rydberg spectra of H2O and D2O are discussed—a \\nCoriolis coupled asymmetric top model for the room temperature 3d←1b1 cluster, and an extension of \\nmultichannel quantum defect theory to asymmetric tops, which is applied to recent jet cooled photoionization \\nspectra of the nd←1b1 series converging to the (100) vibrational levels of H2O\",\"PeriodicalId\":296295,\"journal\":{\"name\":\"Laser Chemistry\",\"volume\":\"39 10\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Laser Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/LC.11.253\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Laser Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/LC.11.253","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Rotational Analysis of the Rydberg Spectrum of Water
Two techniques for rotational analysis of the nd←1b1 Rydberg spectra of H2O and D2O are discussed—a
Coriolis coupled asymmetric top model for the room temperature 3d←1b1 cluster, and an extension of
multichannel quantum defect theory to asymmetric tops, which is applied to recent jet cooled photoionization
spectra of the nd←1b1 series converging to the (100) vibrational levels of H2O
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