生物质制备生物乙醇研究进展

N. Verma
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引用次数: 2

摘要

随着对全球变暖和对化石燃料依赖的担忧日益加剧,寻找减少二氧化碳排放的可再生能源成为一个广泛关注的问题。为了减少温室气体对大气的净贡献,乙醇已被认为是石油衍生运输燃料的潜在替代品。从生物质(生物乙醇)中生产乙醇是减少原油消耗和环境退化的一种方法。可生物降解,毒性低,泄漏对环境污染小。与汽油相比,生物乙醇具有辛烷值高、可燃性极限宽、燃烧速度快、汽化热高的特点。这些特性允许更高的压缩比,更短的燃烧时间和更少的燃烧发动机,这使得内燃机的理论效率优于汽油。生物乙醇目前占全球生物燃料产量的94%以上。由于其低成本和高可用性,预计木质纤维素生物质将为中长期的生物乙醇生产提供很大一部分原料。纤维素材料作为可再生资源的成功利用取决于经济上可行的纤维素酶生产工艺技术的发展。纤维素酶在生物质生产生物乙醇中起着至关重要的作用。生物质的水解通常是通过纤维素水解酶的作用和称为同步糖化和发酵过程(SSF)的顺序过程来进行的。纤维素酶生产是纤维素生物质生产乙醇过程中最昂贵的步骤,约占总成本的40%。为了提高纤维素酶生产技术的商业可行性,需要大幅降低成本。因此,需要加大努力,通过改进发酵技术来高效生产乙醇。降低纤维素酶的成本可以通过使用更便宜的原料和经济上可行的发酵策略来实现。任何可以降低纤维素酶生产成本的策略,都可以显著降低生物乙醇的成本。本文重点介绍了从木质纤维素废弃物中生产生物乙醇及其降低成本的策略。
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Bioethanol from Biomass: A Review
As concern about global warming and dependence on fossil fuels grows, the search for renewable energy sources that reduce CO2 emissions becomes a matter of widespread attention. To reduce the net contribution of GHGs to the atmosphere, ethanol has been recognized as a potential alternative to petroleum-derived transportation fuels. Production of ethanol from biomass (bioethanol) is one way to reduce both consumption of crude oil and environmental degradation. It is biodegradable, low in toxicity and causes little environmental pollution if spilt. Bioethanol has higher octane number, broader flammability limit, higher flame speed and higher heat of vaporization than gasoline. These properties allow for a higher compression ratio, shorter burn time and leaner burn engine, which lead to theoretical efficiency advantages over gasoline in an internal combustion engine. Bioethanol currently accounts for more than 94% of global biofuel production. Lignocellulosic biomass is envisaged to provide a significant portion of the feedstocks for bioethanol production in the medium and long form due to their low cost and high availability. Successful utilization of cellulosic materials as renewable resources is dependent on the development of economically feasible process technologies for cellulase production. Cellulase plays a vital role in the production of bioetanol from biomass. Hydrolysis of biomass is usually carried out by the action of cellulolytic enzymes and the sequential process called Simultaneous Saccharification and Fermentation process (SSF). Cellulase production is the most expensive step during ethanol production from cellulosic biomass, and accountes for approximately 40% of the total cost. Significant cost reduction is required in order to enhance the commercial viability of cellulase production technology. Therefore, efforts are to be intensified to produce ethanol efficiently through improved fermentation technologies. Reduction in the cost of cellulases can be achieved by use of cheaper raw materials and economically viable fermentation strategies. Any strategies which can bring down the production cost of cellulases, can significantly reduce the cost of bioethanol. In the present paper, bioethanol production from lignocellulosic wastes and their cost reduction strategies are highlighted.
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