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引用次数: 0

摘要

开发了以1,3,5-三嗪衍生物(3N-T2T)为电子受体,以咔唑衍生物(Tris-PCz)为电子给体的高效外络合物体系。我们采用仅由Tris-PCz和3N-T2T组成的简单器件结构作为电荷传输和发射材料。Tris-PCz和3N-T2T的空穴迁移率和电子迁移率、ITO向EML的无势垒空穴注入和高三重态能量的结合,使得绿色杂化器件在1000 cdm-2下实现了3.4 V的极低驱动电压和高达10.8% (32.7 cda - 1,38.4 lm W-1)的最大EQE。
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High performance green exciplex OLED
Highly efficient exciplex systems incorporating a 1,3,5-triazine derivative (3N-T2T) as an electron acceptor and caibazole derivative (Tris-PCz) as an electron donor are developed. We employed a simple device structure composed of only Tris-PCz and 3N-T2T as charge-transporting and emitting materials. The combination of the hole and electron mobility of Tris-PCz and 3N-T2T, respectively, the barrier free hole injection from the ITO to the EML and high triplet energies renders the green exciplex device to realize an exceptionally low driving voltage of 3.4 V at 1000 cdm-2 and maximum EQE up to 10.8% (32.7 cdA-1, 38.4 lm W-1).
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