iii -氮化物基太阳能电池InXGa1−xN/GaN量子阱结构的光谱分析

D. O'Mahony, P. Parbrook, B. Corbett, J. Kovác, M. Florovič, A. Vincze
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摘要

本文报道了iii -氮化物外延结构可见光吸收的光学和电学特性。结合InxGa1-xN/GaN (0.20<;x<;0.35)量子阱活性区的结构通过光电流光谱、光学传输和电/光致发光技术进行了分析,以确定结构的关键光谱吸收特性。此外,还研究了铟的组成和量子阱数对这类结构的光谱响应的影响。为了证明不同铟成分对InGaN太阳能电池光伏性能的影响,将一个有源硅太阳能电池堆叠在两个不同铟成分的InGaN结构下。对于较高的铟成分,在零偏置下观察到较低的光谱响应,相应的量子效率降低了约两倍。所获得的结果提供了如何在多结配置中设计包含iii -氮化物太阳能电池的多结太阳能电池,以提高传统电池材料(如硅)的整体效率。
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Spectral analysis of InXGa1−xN/GaN quantum well structures for III-nitride based solar cells
This paper reports on the optical and electrical characteristics of III-nitride epi-structures for visible wavelength absorption. Structures, incorporating InxGa1-xN/GaN (0.20<;x<;0.35) quantum well active regions have been analysed by photocurrent spectroscopy, optical transmission and electro/photo-luminescence techniques to identify the key spectral absorption characteristics of the structures. In addition the influence of indium composition and number of quantum wells on the spectral response of such structures was investigated. In order to demonstrate the effect of different indium compositions on the photovoltaic performance of an InGaN solar cell, an active silicon solar cell was stacked under two InGaN structures with differing indium composition. For higher indium composition, a lower spectral response is observed at zero bias and correspondingly lower quantum efficiency by a factor of approximately two. The obtained results provide insight how multi-junction solar cells incorporating III-nitride solar cells might be designed in a multi-junction configuration in order to boost the overall efficiency of conventional cell materials such as silicon.
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