麻疯树油共溶剂法生产生物柴油

Manjula Jain, Moina Athar
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摘要

本研究的目的是为在最短的反应时间内生产高纯度生物柴油的优良助溶剂工艺提供信息和知识。麻疯树油与甲醇在催化剂存在下的酯交换反应是在非均相体系中发生的,因为反应物不易相互混溶。因此,由于酯交换过程是批处理过程,导致反应时间较长,因此固定资本投资和产品成本较高。为了加快反应速度,提高脂肪酸甲酯的产率,加入了混合溶剂四氢呋喃,使反应在一个相中进行。考察了THF用量、催化剂用量、甲醇体积%和反应时间等参数对酯交换反应的影响。根据ASTM方法进行了不同的测试,以检查生产的生物柴油的各种特性,并根据ASTM D-6751找到。
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Production of Biodiesel by Jatropha Oil Using Co-Solvent Method
The purpose of this research is to provide the information and knowledge about the excellent co-solvent process to produce the high-purity biodiesel with minimum reaction time. Transesterification reaction of Jatropha oil with methanol in the presence of catalyst occurs in a heterogeneous system because the reactants are not readily miscible to each other. As a result, this leads to a longer reaction time and so higher fixed capital investment and product cost due to transesterification process is batch process. To speed up the reaction rate and to increase the fatty acid methyl ester yield, a mixing solvent tetrahydrofuran were added, which enables the reaction to be in one phase. The influence of various parameters on the transesterification reaction including the amount of THF, the amount of catalyst, methanol volume % and reaction time were investigated. Different tests according to ASTM methods were conducted to check the various properties of produced biodiesel and found according to ASTM D-6751.
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