水稻和玉米秸秆生物乙醇燃料的特性:比较研究

Abubakar K. Rabiu, C. M. Elinge, M. M. Ambursa, A. Rabiu, D. Samaila
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引用次数: 1

摘要

以水稻和玉米秸秆为原料,研究了生物乙醇的制备及其特性。通过稀酸水解、发酵和蒸馏生产生物乙醇;馏分用4A沸石脱水提纯。对生物乙醇馏出物的理化性质和燃料性质进行了评价,包括pH值、折射率、比重、闪点、辛烷值和热值。利用FTIR和GC-MS对生物燃料进行了进一步表征。结果表明,玉米秸秆生物乙醇的辛烷值、热值和比重均显著高于水稻秸秆生物乙醇(p<0.05)。同时,两种木质纤维素基质生产的生物乙醇的闪点、折射率、pH、倒点和浊点均无统计学差异(p < 0.05)。pH值、辛数、比重和闪点均在ASTM标准范围内,折射率、云量和凝结点略超出ASTM标准。这揭示了该原料作为生物乙醇生产来源的潜力。
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Characterization of Bioethanol Fuel from Rice and Corn Straws: A Comparative Study
In this study, the production and characterization of bioethanol from rice and corn straws were investigated.The bioethanol was produced through dilute acid hydrolysis, fermentation and distillation; and the distillateswere purified by dehydration using zeolite 4A. The physicochemical and fuel properties of the bioethanoldistillates including pH, refractive index, specific gravity, flash point, octane rating and calorific or heatingvalue were evaluated. Further characterization of the biofuel was carried out using FTIR and GC-MS. Theresults indicated that octane number, calorific value, and specific gravity of the corn straw bioethanol obtainedwere significantly higher (p<0.05) compared to rice straw bioethanol. Meanwhile, no statistically significantdifference (p˃0.05) was observed in the flash point, refractive index, pH, pour and cloud points of thebioethanol produced from the two lignocellulosic substrates. Furthermore, the results reveal that pH, octanenumber, specific gravity and flash point are within the ASTM standards while refractive index, cloud and pourpoint were slightly outside the ASTM standard. This reveal potential of the feedstock as a source for Bioethanolproduction.
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