钠基膨润土对再生塑料复合材料作为潜在土工膜性能的影响

Dahl Kristine Kim Alonzo, Dianne Salino Salino, Runette Villaroza, Roy Trinidad, Donamel M. Saiyari
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摘要

本文研究了消费后废塑料袋作为潜在土工膜在垃圾填埋场的利用。本研究促进了Adamson大学校园内塑料垃圾的回收利用,支持了政府在《生态固体废物管理法》中的倡导。为了确定塑料的成分,对塑料包装袋进行了傅里叶变换红外光谱分析。FTIR结果表明,塑料由聚丙烯(PP)、聚乙烯(PE)和聚酯(PET)制成。随后,将钠基膨润土(SB)按重量的0%、5%、10%和15%的不同比例添加到废塑料碎片中。然后,对其进行熔体插接和压缩成型工艺制备再生塑料复合材料(RPC)。差示扫描量热法(DSC)被用来确定熔体嵌入和压缩成型温度。因此,RPC进行了不同的物理力学测试,如密度、吸水率、弯曲、拉伸、izod冲击和磨损测试。含硫量为15%的RPC吸水能力和抗拉强度最大,含硫量为10%的RPC密度和抗折强度最高。含5% SB的RPC具有最高的冲击强度和耐磨性。扫描电镜(SEM)揭示了聚合物共混物之间的界面附着力差和SB与再生塑料的不均匀分散。总体而言,表面响应优化证实了SB在含量为10.4%时达到了极限百分比,具有很大的土工膜潜力。
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EFFECTS OF SODIUM BENTONITE ON THE CHARACTERISTICS OF RECYCLED PLASTICCOMPOSITES AS POTENTIAL GEOMEMBRANE
This paper investigates the utilization of post--consumer waste plastic sachets as potential geomembrane in landfills. This study promotes recycling of plastic wastes in Adamson University premises and supports the government advocacy in Ecological Solid Waste Management Act. To confirm the plastic compositions, the plastic waste sachets were subjected to Fourier Transformed Infrared (FTIR) Spectroscopy analysis. FTIR result shows that plastics were made of polypropylene (PP), polyethylene (PE), and polyester (PET). Subsequently, sodium bentonite (SB) was added to shredded waste plastics at varying percentages of 0, 5, 10 and 15 percent by weight. Then, it was subjected to melt intercalation and compression molding process to produce recycled plastic composites (RPC). Differential scanning calorimetry (DSC) was performed to determine the melt--intercalation and compression molding temperatures. Consequently, RPC was subjected to different physico--mechanical tests such as density, water absorption, flexural, tensile, izod impact and abrasion tests. Maximum water absorption capacity and tensile strength were observed in RPC with 15% SB. The highest density and flexural strength were observed in RPC with 10% SB content. Moreover, RPC with 5% SB exhibited the highest impact strength and abrasive resistance. Scanning Electron Microscopy (SEM) divulged the poor interfacial adhesion between the polymer blends and unequal dispersion of SB with recycled plastics. Overall, the surface response optimization corroborates that the ultimate percentage of SB was achieved at 10.4% content which has a great potential as geomembrane.
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