闪光灯熔覆法在SiOx中形成nc-Si

N. Yoshioka, A. Heya, Naoto Matuo, Yousuke Nakamura, Gakuhiko Yokomori, M. Yoshioka, K. Kohama, Kazuhiro Ito
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摘要

在SiOx中形成纳米晶硅(nc-Si)是实现高质量太阳能电池的关键技术之一。通过反应溅射将SiOx薄膜沉积在石英衬底上。SiOx薄膜的Si/O比由0.56提高到2.07。用拉曼散射光谱对SiOx薄膜中的nc-Si进行了表征。所有样品经FLA处理后结晶率几乎为100%。通过拉曼峰位置估计nc-Si的尺寸为9 nm。结果表明,Si/O比值对nc-Si的晶粒尺寸没有影响。另一方面,SiOx薄膜的Si/O比改变了晶体相引起的拉曼峰半峰全宽度(FWHM)。
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Formation of nc-Si in SiOx by flash lamp anneling
The formation of nanocrystal silicon (nc-Si) in SiOx is one of the key technologies for the realization of high-quality solar cells. The SiOx films were deposited on a quartz substrate by a reactive sputtering. The Si/O ratio of the SiOx films were changed from 0.56 to 2.07. The nc-Si in SiOx film was characterized by Raman scattering spectroscopy. The Crystalline fractions of all samples after FLA were almost 100%. The size of nc-Si was estimated to 9 nm by Raman peak position. It is shown that the grain size of nc-Si was not changed by the Si/O ratio. On the other hand, the full width at half maximum (FWHM) of Raman peak due to crystal phase was changed by the Si/O ratio of SiOx film.
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