多铁BaTiO3-NiFe2O4复合陶瓷的结构、介电、电学和磁性能

N. Ortega, Ashok Kumar, R. Katiyar
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引用次数: 1

摘要

研究了传统固相法制备的BiFeO3 (BTO)1¿× NiFe2O4 (NFO)x (x = 0.05, 0.1, 0.15, 0.2, 0.3, 0.4)多铁复合陶瓷的结构、微观、磁化和介电性能。x射线衍射、拉曼光谱和扫描电镜显示复合材料中存在组成相。在100 Hz ~ 1 MHz范围内,随着NFO浓度的增加,复合材料的介电常数随频率的变化表明,随着NFO浓度的增加,复合材料的¿¿和显著的频率色散随损耗正切的增加而减少。BTO-NFO复合材料在室温下表现出明显的磁滞回线。磁化强度的温度变化表明复合材料在BTO相变(正交四边形)附近的临界值(x=0.40)表现出间接的逆磁电耦合。
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Structural, dielectric, electrical and magnetic properties of multiferroic BaTiO3-NiFe2O4 composite ceramic
Structural, microscopic, magnetization, and dielectric properties of the multiferroic composite ceramics consisting of BiFeO3 (BTO)1¿x¿NiFe2O4 (NFO)x (x = 0.05, 0.1, 0.15, 0.2, 0.3, 0.4) prepared by conventional solid state route were investigated. The x-ray diffraction, Raman spectra, and SEM micrographs showed the presence of constituent phases in the composite. The variation of the dielectric constant with frequency in the range of 100 Hz to 1 MHz shows both, decrease in ¿¿ and significant frequency dispersion accompanied with an increase in the loss tangent, with increase in NFO concentration in the composites. The BTO-NFO composites exhibited well-defined magnetic hysteresis loops at room temperature. The temperature variation of the magnetization showed indirect converse magneto electric coupling for the critical value (x=0.40) of the composite near the BTO phase transition (orthorhombic-tetragonal).
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