MOS2/WS2范德华异质结构的制备与表征

Janani K M, Ashok Kumar L
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摘要

超薄类石墨烯二维(2D)过渡金属二硫族化合物(TMDCs)由于其基本有趣的性质,近年来引起了广泛的研究兴趣。结合不同的材料来获得每种化合物的优异性能,并根据前提条件对其进行调整,是成功制造许多新型器件的基础。通过这种方式,可以将各种2D材料组合在一起,以制造出广泛应用的新设备。MoS2和WS2是两种具有优异电子和光学性能的TMDCs。由于这些是原子薄层状材料,并且由弱范德华力保持,因此更容易将它们剥离成薄片,因此不同材料的组合排列被称为范德华异质结构。我们在这里的动机是利用机械剥离技术,该技术能够产生纯高结晶的TMDCs (MoS2和WS2)原子薄层。然后将这些层堆叠在一起形成范德华异质结构,然后详细研究其基本性质。从几种显微技术获得的数据中研究了形态和地形特性。它的光学和振动特性是由各种光谱技术仔细检查。我们从光学成像和拉曼散射中获得的数据,可以深入了解薄片的厚度和边缘效应。MoS2和WS2的吸收光谱及其异质结构揭示了电子能带结构的几个有趣性质。然后,这些特性可以在几个领域进行探索和实际应用,以制造能量存储设备,柔性和透明电子产品,薄电子产品,开关设备,光电探测器等。
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Fabrication and characterization of MOS2/WS2 van der waal’s heterostructure
Ultrathin graphene-like two-dimensional (2D) transition-metal dichalcogenides (TMDCs) due to their fundamentally intriguing properties have attracted a wide range of research interest in recent days. Combining different materials to obtain the elite properties of each compound and tuning them according to the prerequisite has been the grounds for the successful fabrication of a number of novel devices. In such a manner, various 2D materials can be brought together to concoct new devices for a broad range of applications. MoS2 and WS2 are two such TMDCs with excellent electronic and optical properties. Since these are atomically thin layered materials and are held by a weak van der Waals force, it is easier to peel them apart to form thin sheets, and hence the combined arrangement of different materials is named as van der Waals heterostructure. Our motive here is to make use of the mechanical exfoliation technique, which has the ability to yield a pure highly crystalline atomically thin layer of TMDCs (MoS2 and WS2). These layers are then stacked one above the other to form van der Waals heterostructure, whose fundamental properties are then studied in detail. The morphological and topographical properties are investigated from the data obtained from several microscopic techniques. Its optical and vibrational properties are scrutinized from various spectroscopic techniques. The data we acquired from optical imaging and Raman scattering, gives an insight into the thickness and edge effects of the flake. The absorption spectrum of MoS2, WS2, and their heterostructure reveal several interesting properties of the electronic band structure. These properties can then be explored and incorporated practically in several fields to fabricate energy storage devices, flexible and transparent electronics, thin electronics, switching devices, photodetectors, etc.
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