基于界面改性的水泥混凝土力学性能及机理研究

Jiachen Ma, B. Yan
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引用次数: 1

摘要

为了提高混凝土的力学性能,选用活性外加剂硅灰替代水泥,研究了硅灰对水泥浆体和混凝土力学性能的影响。采用扫描电镜(SEM)和x射线衍射(XRD)研究了硅灰对混凝土的包晶作用机理。结果表明,硅灰的掺入对水泥浆体的力学性能没有明显改善。界面改性对水泥混凝土28d抗压强度有较大提高。当硅灰掺量为10%时,界面改性水泥混凝土的抗压强度比未改性水泥混凝土提高26.4%。对比界面改性前后混凝土的SEM图像,硅灰改善了混凝土界面的结构和密度,改善了界面水化产物CH的排列。硅灰具有充填效果和与CH发生火山灰反应的特点,随着硅灰用量的增加,CH含量降低,C3S和SiO2含量增加。利用硅灰与水化产物之间的物理化学相互作用,可以达到混凝土界面改性的效果。
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Study on the mechanical properties and mechanism of cement concrete based on interface modification
In order to improve the mechanical properties of concrete, silica fume, an active admixture, was selected to replace cement and the effect of silica fume on the mechanical properties of cement paste and concrete was investigated. The mechanism of the peritectic effect of silica fume on concrete was investigated by SEM and XRD. The results showed that the incorporation of silica fume did not improve the mechanical properties of cement paste significantly. The 28d compressive strength of cement concrete based on interfacial modification was improved to a greater extent. When the amount of silica fume was 10%, the compressive strength of cement concrete based on interface modification was increased by 26.4 % compared with that of unmodified concrete. Comparing the SEM images of concrete before and after the interface modification, silica fume improved the structure and density of concrete interface, as well as the arrangement of hydration products CH at the interface. The silica fume has the characteristics of filling effect and pozzolanic reaction with CH. As the amount of silica fume increases, the CH content decreases and the C3S and SiO2 increase. By using the physical and chemical interaction between silica fume and hydration products, the effect of concrete interface modification can be achieved.
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