超长纳米复合钢丝绳

Marco A. Marini, M. Talò, G. Lanzara, W. Lacarbonara
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摘要

碳纳米管(CNT)是一种有效的聚合物基质填料。它们的物理性质使它们能够发挥显著的强化作用,而它们的纳米尺度使聚合物的重量保持不变。利用其高强度重量比,碳纳米管/聚合物纳米复合材料似乎是形成电线和纤维的理想材料。在这项工作中,提出了一种特殊的创新挤出工艺来制造透长和超长碳纳米管/聚合物纳米复合线。通过对工艺参数进行微调,制备出具有最佳机械性能的纳米复合材料长丝。光学分析证实了制备的平均直径为350 μm的细丝的形态特征。进行了单调拉伸试验,以研究CNTs含量为1wt %至3wt %的钢丝的力学响应。与纯聚合物丝相比,3 wt%碳纳米管纳米复合丝的杨氏模量和抗拉强度分别增加了47%和43%。最后,采用循环拉伸试验来研究碳纳米管融入聚合物基体后阻尼能力的变化。这种经过优化的碳纳米管复合线可以很容易地集成到几个设备中,或者组装成具有多功能和改进性能的绳索和纱线。
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Ultra-Long Nanocomposite Wire Ropes
Carbon nanotubes (CNT) represent an effective filler to be incorporated into polymer matrices. Their physical properties allow them to exert a remarkable strengthening effect, while their nano-scale leaves the polymer weight unaltered. Exploiting their high strength-to-weight ratio, CNT/polymer nanocomposites appear to be the ideal materials to be shaped as wires and fibers. In this work, an ad-hoc innovative extrusion process is proposed to fabricate though and ultralong CNT/polymer nanocomposite wires. The process parameters are finely tuned to produce nanocomposite filaments exhibiting optimized mechanical properties. Optical analyses validate the morphological features of the fabricated filaments having an averaged diameter of 350 μm. Monotonic tensile tests are carried out to investigate the mechanical response of wires with CNTs content ranging from 1 wt% to 3 wt%. Young’s modulus and tensile strength registered increments of 47% and 43%, respectively, when comparing the 3 wt% CNT nanocomposite wires with the neat polymer wires. Finally, cyclic tensile tests are employed to investigate the change in damping capacity that accompanies the integration of CNTs into the polymer matrix. Such optimized CNTs nanocomposite wires can be easily integrated into several devices or assembled into ropes and yarns with multifunctional, improved properties.
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