用常压化学气相沉积法在溅射铜岛上生长碳纳米管,用于生物传感器

Anis Amirah Alim, Roharsyafinaz Roslan, Sh. Nadzirah, M. Nassir, Weihong Zhang, A. Ismail, Dee Chang Fu, Mohd Ambri Mohammed, J. Yunas, M. R. Buyong, A. A. Hamzah
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引用次数: 0

摘要

通过溅射在硅片上沉积铜,然后在常压下进行热退火,可以形成铜岛。通过退火脱湿铜催化剂促进了自组装碳纳米管(CNT)在铜岛上的生长。在无真空室中,在1000$^{\circ}C$的温度下,对几纳米溅射铜薄膜进行氩气退火,以促进铜薄膜的脱湿过程。在实验室内提供$40 cm^{3}$/min的甲烷气体来生长碳纳米管。由于该技术制备简单且具有批量生产的潜力,因此与其他制备纳米催化剂的方法相比,我们选择了脱湿技术。利用原子力显微镜(AFM)和场发射扫描电子显微镜(FESEM)研究了样品的形貌。通过拉曼分析来确定碳纳米管的质量与D,G, G '和D峰的存在。在直流模式下,测量得到的电流为55.3 $\mu A$。因此,碳纳米管作为高灵敏度和快速检测传感系统的最有潜力的组成部分之一受到了广泛的关注。
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Carbon nanotubes grown on sputtered copper islands using atmospheric pressure chemical vapor deposition for biosensor applications
As-deposited copper on silicon wafer by sputtering and subsequent thermal annealing at atmospheric pressure enables the formation of copper islands. Dewetting of copper catalyst by annealing promotes the growth of self-assembly carbon nanotubes (CNT) on the copper islands. A few nanometers sputtered copper thin film was annealed with the presence of argan gas in vacuum-less chamber under 1000$^{\circ}C$ to promote the dewetting process of copper thin film. $40 cm^{3}$/min of methane gas was supplied inside the chamber to grow the CNT. Due to this fabrication simplicity with the potential for mass production, dewetting technique was chosen compared to other preparation of catalyst nanoparticles method. Atomic Force Microscopy (AFM) and Field Emission Scanning Electron (FESEM) were done to study the morphology of the sample. Raman analysis was done to identify the quality of CNT with the presence of D,G, G’ and D peaks. The current obtained in the measurement was 55.3 $\mu A$ in DC mode. Thus, CNT has garnered much attention as one of the most potential building blocks for high sensitivity and rapid detection sensing system.
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