{"title":"解决甲醇净化“呼吸”气体的环境问题","authors":"V. Bochkarev, O. Kukurina, A. Vdovin","doi":"10.1109/IFOST.2012.6357489","DOIUrl":null,"url":null,"abstract":"The true reasons of decrease in efficiency of \"breathing\" gases cleaning of tanks and railway tanks from methanol on CJSC \"Methanol\" (Tomsk, Russia) are determined. Platinum catalyst aging is caused by sintering and partial destruction of ceramic blocks owing to excess of ultimate service temperature, blocking of the active centers by coke, nonoptimum working of the catalytic installation. The economic way of block platinum catalysts regeneration is developed. Also the kinetics of the methanol deep oxidation on platinum and metal-complex catalysts is investigated. Moreover optimal operation of installation for \"breathing\" gases purification is defined.","PeriodicalId":319762,"journal":{"name":"2012 7th International Forum on Strategic Technology (IFOST)","volume":"42 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2012-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Solving environmental problems of “breathing” gases purification from methanol\",\"authors\":\"V. Bochkarev, O. Kukurina, A. Vdovin\",\"doi\":\"10.1109/IFOST.2012.6357489\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The true reasons of decrease in efficiency of \\\"breathing\\\" gases cleaning of tanks and railway tanks from methanol on CJSC \\\"Methanol\\\" (Tomsk, Russia) are determined. Platinum catalyst aging is caused by sintering and partial destruction of ceramic blocks owing to excess of ultimate service temperature, blocking of the active centers by coke, nonoptimum working of the catalytic installation. The economic way of block platinum catalysts regeneration is developed. Also the kinetics of the methanol deep oxidation on platinum and metal-complex catalysts is investigated. Moreover optimal operation of installation for \\\"breathing\\\" gases purification is defined.\",\"PeriodicalId\":319762,\"journal\":{\"name\":\"2012 7th International Forum on Strategic Technology (IFOST)\",\"volume\":\"42 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2012-11-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2012 7th International Forum on Strategic Technology (IFOST)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/IFOST.2012.6357489\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2012 7th International Forum on Strategic Technology (IFOST)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/IFOST.2012.6357489","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Solving environmental problems of “breathing” gases purification from methanol
The true reasons of decrease in efficiency of "breathing" gases cleaning of tanks and railway tanks from methanol on CJSC "Methanol" (Tomsk, Russia) are determined. Platinum catalyst aging is caused by sintering and partial destruction of ceramic blocks owing to excess of ultimate service temperature, blocking of the active centers by coke, nonoptimum working of the catalytic installation. The economic way of block platinum catalysts regeneration is developed. Also the kinetics of the methanol deep oxidation on platinum and metal-complex catalysts is investigated. Moreover optimal operation of installation for "breathing" gases purification is defined.
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