在硅串联太阳能电池上单片生长的InxGa1−xAs纳米线具有高效率

J. Shin, K. Kim, Hefei Hu, Ki Jun Yu, J. Rogers, J. Zuo, Xiuling Li
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摘要

III-V和Si的异质外延集成已经研究多年,因为Si是主流的平台,III-V可以用作发光源(即直接带隙)[1]。虽然已经有几个研究小组证明了在Si衬底(11.6%晶格错配)上不使用催化剂和图图化的垂直InAs纳米线(NWs)生长[2,3],但三元InxGa1−xAs纳米线的直接异外延生长尚未得到系统研究,尽管它在近红外范围内具有重要的光谱覆盖范围。在本文中,我们报道了在硅(111)衬底上无位错的InxGa1−xAs纳米线在整个组成范围内的一维异质外延生长,并证明了由InxGa1−xAs NWs组成的单片轴向p-n结串联太阳能电池的效率远远超过使用相同工艺制作的平面Si单结太阳能电池。
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Monolithically grown InxGa1−xAs nanowire on silicon tandem solar cells with high efficiency
Heteroepitaxial integration of III–V and Si has been researched for many years since the Si is the prevalent platform and III–V can be used for light emitting source (i.e., direct bandgap) [1]. Although vertical InAs nanowires (NWs) growth on Si substrate (11.6% lattice mismatch) without catalysts and patterning has been demonstrated by several groups, [2, 3], direct heteroexpitaxial growth of ternary InxGa1−xAs nanowires hasn't been systematically studied yet, in spite of its important spectral coverage in the near infrared range. In this paper, we report the one-dimensional heteroepitaxial growth of dislocation free InxGa1−xAs nanowires on silicon (111) substrate in the entire composition range and demonstrate monolithically grown axial p-n junction tandem solar cells consisting of InxGa1−xAs NWs on Si with an efficiency that well exceeds the planar Si single junction solar cell fabricated using identical process.
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