均相沉淀法制备不同ZnO结构

M. R. Herrera-Rivera, Ana M. Pineda, A. Maldonado-Alvarez, M. D. L. L. Olvera-Amador
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引用次数: 0

摘要

采用均匀沉淀法制备了具有介孔结构的氧化锌粉体。以二水合乙酸锌(Zn(CH3COO)2.2H2O)为锌源,碳酸铵(NH4)2CO3)为沉淀剂,合成了氧化锌纳米颗粒。研究了分子浓度(0.05、0.5和0.35 M)、饱和度、合成温度(30和70°C)和合成时间(30、60和120 min)的变化对结构和形态的影响。x射线衍射(XRD)结果证实了ZnO相的存在。通过透射电子显微镜(TEM)和扫描电子显微镜(SEM)表征分析了颗粒的形态(大小和形状)。
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Different ZnO structures prepared by homogeneous precipitation method
Mesoporous structures of zinc oxide (ZnO) powders were prepared by the homogenous precipitation method. ZnO nanoparticles were synthesized from a solution of zinc acetate dihydrate (Zn(CH3COO)2.2H2O) as zinc source and ammonium carbonate ((NH4)2CO3) as precipitant agent. Structural and morphological characteristics were studied with respect to changes in molarity (0.05, 0.5, and 0.35 M), percentage of saturation, synthesis temperature (30, and 70°C), and time (30, 60, and 120 min). ZnO phases were confirmed from X-ray Diffraction (XRD) results. The particles morphology (size and shape) was analyzed from the Transmission Electron Microscopy (TEM) and Scanning Electron Microscopy (SEM) characterization.
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