纳米结构控制下改性CNT和GnP-PVDF复合材料的声光电性质和界面耐久性

Joung-Man Park, D. Kwon, Zuo-Jia Wang, L. DeVries
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摘要

改性碳纳米管(CNT)和石墨烯纳米板(GnP)的纳米和异质结构可以作为声致动器在微机电系统(MEMS)中显著控制压阻和光电子性能。研究了聚偏氟乙烯(PVDF)纳米复合材料中改性碳纳米管和GnP的界面耐久性和电性能。由于其独特的电学性质,改性GnP包覆PVDF纳米复合材料比纯碳纳米管和改性碳纳米管表现出更好的导电性。改性的GnP涂层也表现出良好的声学性能。通过接触角、表面能、粘附功和扩散系数的测量,探讨了纯碳纳米管或等离子体处理的碳纳米管与等离子体处理的PVDF之间的界面粘附耐久性。利用声级计研究了不同曲率半径和不同涂层条件下改性GnP包覆PVDF纳米复合材料的声致动性能。由于改进的电性能,改进的GnP可以成为比碳纳米管更合适的声学致动器。得到了最适宜声压级性能的曲率半径和涂层厚度。该研究可为高质量透明声致动器的制造参数提供实用依据。
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Acoustic and optoelectronic nature and interfacial durability of modified CNT and GnP-PVDF composites with nanostructural control
Nano- and hetero-structures of modified carbon nanotube (CNT) and Graphene nano Platelet (GnP) can control significantly piezoresistive and optoelectronic properties in Microelectromechanical Systems (MEMS) as acoustic actuators. Interfacial durability and electrical properties of modified CNT and GnP embedded in poly (vinylidene fluoride) (PVDF) nanocomposites were investigated for use in acoustic actuator applications. Modified GnP coated PVDF nanocomposite exhibited better electrical conductivity than neat and modified CNT due to the unique electrical nature of GnP. Modified GnP coating also exhibited good acoustical properties. Contact angle, surface energy, work of adhesion, and spreading coefficient measurements were contributed to explore the interfacial adhesion durability between neat CNT or plasma treated CNT and plasma treated PVDF. Acoustic actuation performance of modified GnP coated PVDF nanocomposites were investigated for different radii of curvature and different coating conditions, using a sound level meter. Modified GnP can be a more appropriate acoustic actuator than CNT cases because of improved electrical properties. Optimum radius of curvature and coating thickness was also obtained for the most appropriate sound pressure level (SPL) performance. This study can provide manufacturing parameters of transparent sound actuators with good quality practically.
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